Palladium-Based Anion- Exchange Membrane Fuel Cell Using KOH- Doped Polybenzimidazole as the Electrolyte

被引：18

作者：

Fujigaya, Tsuyohiko ^{[1
,2
]}

Kim, ChaeRin ^{[1
]}

Matsumoto, Kazuya ^{[1
]}

Nakashima, Naotoshi ^{[1
,2
,3
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Appl Chem, Nishi Ku, Fukuoka 8190395, Japan

[2] Kyushu Univ, World Premier Int WPI Res Ctr, Int Inst Carbon Neutral Energy Res I2CNER, Nishi Ku, Fukuoka 8190395, Japan

[3] JST CREST, Chiyoda Ku, Tokyo 1020075, Japan

来源：

CHEMPLUSCHEM | 2014年 / 79卷 / 03期

关键词：

fuel cells; ion exchange; nanotubes; oxygen reduction reaction; palladium; OXYGEN REDUCTION REACTION; ALKALINE POLYMER ELECTROLYTE; CARBON NANOTUBES; CONDUCTING MEMBRANES; PD NANOPARTICLES; HIGH-TEMPERATURE; CATALYSTS; ELECTROCATALYST; ELECTROREDUCTION; PERFORMANCE;

D O I：

10.1002/cplu.201300377

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The development of a low-cost and high-performance fuel cell is a strong social demand. Anion-exchange membrane fuel cells (AEMFCs) have recently emerged as an alternative technology to conventional fuel cells that use a proton-exchange membrane as they enable the use of cheaper metals than platinum. An AEMFC exhibiting a maximum power density of 241mWcm(-2) based on a palladium-based electrocatalyst has been developed. The polybenzimidazole-wrapped carbon nanotubes were used to anchor the palladium nanoparticles, and the material was doped using KOH to form an ideal triple-phase boundary structure around the palladium. The observed maximum power density is the highest among previously reported AEMFCs using palladium as the metal catalyst.

引用

页码：400 / 405

页数：6

共 50 条

[1] Performance of a Direct Glycerol Fuel Cell using KOH Doped Polybenzimidazole as Electrolyte
Nascimento, Ana P.
Linares, Jose J.
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2014, 25 (03) : 509 - 516
[2] KOH-doped polybenzimidazole membrane for direct hydrazine fuel cell
Wang, Yucheng
Wang, Qi
Wan, Li-yang
Han, Yu
Hong, Yuhao
Huang, Long
Yang, Xiaodong
Wang, Yuesheng
Zaghib, Karim
Zhou, Zhiyou
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2020, 563 : 27 - 32
[3] Proton exchange membrane fuel cell of polybenzimidazole electrolyte doped with phosphoric acid and antimony chloride
Chen, Wei-Chen
Tsai, Dah-Shyang
Tseng, Lin-Wei
Yang, Li-Rong
Le, Minh-Vien
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (19) : 10245 - 10252
[4] Product analysis of the ethanol oxidation reaction on palladium-based catalysts in an anion-exchange membrane fuel cell environment
Shen, S. Y.
Zhao, T. S.
Wu, Q. X.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (01) : 575 - 582
[5] Physicochemical properties of alkaline doped polybenzimidazole membranes for anion exchange membrane fuel cells
Zeng, L.
Zhao, T. S.
An, L.
Zhao, G.
Yan, X. H.
JOURNAL OF MEMBRANE SCIENCE, 2015, 493 : 340 - 348
[6] Current Density Maximization in Palladium-Based Gas Diffusion Electrode in Proton Exchange Membrane Fuel Cell
Bonifacio, Rafael Nogueira
Neto, Almir Oliveira
Linardi, Marcelo
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2013, 8 (04): : 5621 - 5634
[7] Hydrogen/oxygen polymer electrolyte membrane fuel cell (PEMFC) based on acid-doped polybenzimidazole (PBI)
Savadogo, O
Xing, B
JOURNAL OF NEW MATERIALS FOR ELECTROCHEMICAL SYSTEMS, 2000, 3 (04) : 343 - 347
[8] Palladium-based electrodes: A way to reduce platinum content in polymer electrolyte membrane fuel cells
Antolini, Ermete
Zignani, Sabrina C.
Santos, Sydney F.
Gonzalez, Ernesto R.
ELECTROCHIMICA ACTA, 2011, 56 (05) : 2299 - 2305
[9] Membrane Electrode Assembly for High Temperature Polymer Electrolyte Membrane Fuel Cell Based on Phosphoric Acid-Doped Polybenzimidazole
Yao, Dongmei
Zhang, Weiqi
Xu, Qian
Xu, Li
Li, Huaming
Su, Huaneng
PROGRESS IN CHEMISTRY, 2019, 31 (2-3) : 455 - 463
[10] The effect of porosity on performance of phosphoric acid doped polybenzimidazole polymer electrolyte membrane fuel cell
Celik, Muhammet
Genc, Gamze
Elden, Gulsah
Yapici, Huseyin
EFM15 - EXPERIMENTAL FLUID MECHANICS 2015, 2016, 114

← 1 2 3 4 5 →