Palladium-Based Anion- Exchange Membrane Fuel Cell Using KOH- Doped Polybenzimidazole as the Electrolyte

被引：18
作者：
Fujigaya, Tsuyohiko [1 ,2 ]
Kim, ChaeRin [1 ]
Matsumoto, Kazuya [1 ]
Nakashima, Naotoshi [1 ,2 ,3 ]
机构：
[1] Kyushu Univ, Grad Sch Engn, Dept Appl Chem, Nishi Ku, Fukuoka 8190395, Japan
[2] Kyushu Univ, World Premier Int WPI Res Ctr, Int Inst Carbon Neutral Energy Res I2CNER, Nishi Ku, Fukuoka 8190395, Japan
[3] JST CREST, Chiyoda Ku, Tokyo 1020075, Japan
来源：
CHEMPLUSCHEM | 2014年 / 79卷 / 03期
关键词：
fuel cells; ion exchange; nanotubes; oxygen reduction reaction; palladium; OXYGEN REDUCTION REACTION; ALKALINE POLYMER ELECTROLYTE; CARBON NANOTUBES; CONDUCTING MEMBRANES; PD NANOPARTICLES; HIGH-TEMPERATURE; CATALYSTS; ELECTROCATALYST; ELECTROREDUCTION; PERFORMANCE;
D O I：
10.1002/cplu.201300377
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The development of a low-cost and high-performance fuel cell is a strong social demand. Anion-exchange membrane fuel cells (AEMFCs) have recently emerged as an alternative technology to conventional fuel cells that use a proton-exchange membrane as they enable the use of cheaper metals than platinum. An AEMFC exhibiting a maximum power density of 241mWcm(-2) based on a palladium-based electrocatalyst has been developed. The polybenzimidazole-wrapped carbon nanotubes were used to anchor the palladium nanoparticles, and the material was doped using KOH to form an ideal triple-phase boundary structure around the palladium. The observed maximum power density is the highest among previously reported AEMFCs using palladium as the metal catalyst.
引用
收藏
页码：400 / 405
页数：6
相关论文
共 61 条
[1]   Heterogeneous anion conducting membranes based on linear and crosslinked KOH doped polybenzimidazole for alkaline water electrolysis [J].
Aili, David ;
Hansen, Martin Kalmar ;
Renzaho, Richard Fulgence ;
Li, Qingfeng ;
Christensen, Erik ;
Jensen, Jens Oluf ;
Bjerrum, Niels J. .
JOURNAL OF MEMBRANE SCIENCE, 2013, 447 :424-432
[2]   Electroreduction of oxygen on Vulcan carbon supported Pd nanoparticles and Pd-M nanoalloys in acid and alkaline solutions [J].
Alexeyeva, N. ;
Sarapuu, A. ;
Tammeveski, K. ;
Vidal-Iglesias, F. J. ;
Solla-Gullon, J. ;
Feliu, J. M. .
ELECTROCHIMICA ACTA, 2011, 56 (19) :6702-6708
[3]   Palladium in fuel cell catalysis [J].
Antolini, Ermete .
ENERGY & ENVIRONMENTAL SCIENCE, 2009, 2 (09) :915-931
[4]  
Asazawa K., 2007, ANGEW CHEM, V119, P8170, DOI DOI 10.1002/ange.200701334
[5]   A platinum-free zero-carbon-emission easy fuelling direct hydrazine fuel cell for vehicles [J].
Asazawa, Koichiro ;
Yamada, Koji ;
Tanaka, Hirohisa ;
Oka, Akinori ;
Taniguchi, Masatoshi ;
Kobayashi, Tetsuhiko .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (42) :8024-8027
[6]   Study of Anode Catalysts and Fuel Concentration on Direct Hydrazine Alkaline Anion-Exchange Membrane Fuel Cells [J].
Asazawa, Koichiro ;
Sakamoto, Tomokazu ;
Yamaguchi, Susumu ;
Yamada, Koji ;
Fujikawa, Hirotoshi ;
Tanaka, Hirohisa ;
Oguro, Keisuke .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (04) :B509-B512
[7]   A class of non-precious metal composite catalysts for fuel cells [J].
Bashyam, Rajesh ;
Zelenay, Piotr .
NATURE, 2006, 443 (7107) :63-66
[8]   Scientific aspects of polymer electrolyte fuel cell durability and degradation [J].
Borup, Rod ;
Meyers, Jeremy ;
Pivovar, Bryan ;
Kim, Yu Seung ;
Mukundan, Rangachary ;
Garland, Nancy ;
Myers, Deborah ;
Wilson, Mahlon ;
Garzon, Fernando ;
Wood, David ;
Zelenay, Piotr ;
More, Karren ;
Stroh, Ken ;
Zawodzinski, Tom ;
Boncella, James ;
McGrath, James E. ;
Inaba, Minoru ;
Miyatake, Kenji ;
Hori, Michio ;
Ota, Kenichiro ;
Ogumi, Zempachi ;
Miyata, Seizo ;
Nishikata, Atsushi ;
Siroma, Zyun ;
Uchimoto, Yoshiharu ;
Yasuda, Kazuaki ;
Kimijima, Ken-ichi ;
Iwashita, Norio .
CHEMICAL REVIEWS, 2007, 107 (10) :3904-3951
[9]   PEMFCs and AEMFCs directly fed with ethanol: a current status comparative review [J].
Brouzgou, A. ;
Podias, A. ;
Tsiakaras, P. .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2013, 43 (02) :119-136
[10]   Carbon Nanotubes for Sustainable Energy Applications [J].
Centi, Gabriele ;
Perathoner, Siglinda .
CHEMSUSCHEM, 2011, 4 (07) :913-925
1234567