Nitrogen and Sulfur Dual-Doped Non-Noble Catalyst Using Fluidic Acrylonitrile Telomer as Precursor for Efficient Oxygen Reduction

被引：184
作者：
Chang, Yuanqin [1 ,2 ]
Hong, Fei [1 ]
He, Chuanxin [2 ]
Zhang, Qianling [2 ]
Liu, Jianhong [2 ]
机构：
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China
[2] Shenzhen Univ, Sch Chem & Chem Engn, Shenzhen Key Lab Funct Polymer, Shenzhen 518060, Guangdong, Peoples R China
来源：
ADVANCED MATERIALS | 2013年 / 25卷 / 34期
基金：
中国国家自然科学基金;
关键词：
catalysis; fuel cells; doping; hybrid materials; HIGH ELECTROCATALYTIC ACTIVITY; PEM FUEL-CELLS; CARBON NANOTUBES; GRAPHENE OXIDE; O-2; REDUCTION; PYROLYSIS; IRON; POLYANILINE; ARRAYS;
D O I：
10.1002/adma.201301002
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In order to make polyacrylonitrile (PAN) fluidic, acrylonitrile telomer (ANT) is synthesized by radical telomerization and used as a nitrogen and carbon precursor to prepare a non-noble oxygen reduction reaction (ORR) catalyst. This fluidic precursor greatly increases the contact between Fe salt aggregates and the polymer so that more active sites are formed during stabilization and carbonization. Such prepared catalysts and the commercial Pt/C catalyst have comparable ORR performance and stability. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：4794 / 4799
页数：6
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