Nitrogen and Sulfur Dual-Doped Non-Noble Catalyst Using Fluidic Acrylonitrile Telomer as Precursor for Efficient Oxygen Reduction

被引：185
作者：
Chang, Yuanqin [1 ,2 ]
Hong, Fei [1 ]
He, Chuanxin [2 ]
Zhang, Qianling [2 ]
Liu, Jianhong [2 ]
机构：
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China
[2] Shenzhen Univ, Sch Chem & Chem Engn, Shenzhen Key Lab Funct Polymer, Shenzhen 518060, Guangdong, Peoples R China
来源：
ADVANCED MATERIALS | 2013年 / 25卷 / 34期
基金：
中国国家自然科学基金;
关键词：
catalysis; fuel cells; doping; hybrid materials; HIGH ELECTROCATALYTIC ACTIVITY; PEM FUEL-CELLS; CARBON NANOTUBES; GRAPHENE OXIDE; O-2; REDUCTION; PYROLYSIS; IRON; POLYANILINE; ARRAYS;
D O I：
10.1002/adma.201301002
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In order to make polyacrylonitrile (PAN) fluidic, acrylonitrile telomer (ANT) is synthesized by radical telomerization and used as a nitrogen and carbon precursor to prepare a non-noble oxygen reduction reaction (ORR) catalyst. This fluidic precursor greatly increases the contact between Fe salt aggregates and the polymer so that more active sites are formed during stabilization and carbonization. Such prepared catalysts and the commercial Pt/C catalyst have comparable ORR performance and stability. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：4794 / 4799
页数：6
相关论文
共 39 条
[1]   Sp2 C-Dominant N-Doped Carbon Sub-micrometer Spheres with a Tunable Size: A Versatile Platform for Highly Efficient Oxygen-Reduction Catalysts [J].
Ai, Kelong ;
Liu, Yanlan ;
Ruan, Changping ;
Lu, Lehui ;
Lu, Gaoqing .
ADVANCED MATERIALS, 2013, 25 (07) :998-1003
[2]  
[Anonymous], 2001, ELECTROCHEMICAL METH
[3]   A class of non-precious metal composite catalysts for fuel cells [J].
Bashyam, Rajesh ;
Zelenay, Piotr .
NATURE, 2006, 443 (7107) :63-66
[4]   Scientific aspects of polymer electrolyte fuel cell durability and degradation [J].
Borup, Rod ;
Meyers, Jeremy ;
Pivovar, Bryan ;
Kim, Yu Seung ;
Mukundan, Rangachary ;
Garland, Nancy ;
Myers, Deborah ;
Wilson, Mahlon ;
Garzon, Fernando ;
Wood, David ;
Zelenay, Piotr ;
More, Karren ;
Stroh, Ken ;
Zawodzinski, Tom ;
Boncella, James ;
McGrath, James E. ;
Inaba, Minoru ;
Miyatake, Kenji ;
Hori, Michio ;
Ota, Kenichiro ;
Ogumi, Zempachi ;
Miyata, Seizo ;
Nishikata, Atsushi ;
Siroma, Zyun ;
Uchimoto, Yoshiharu ;
Yasuda, Kazuaki ;
Kimijima, Ken-ichi ;
Iwashita, Norio .
CHEMICAL REVIEWS, 2007, 107 (10) :3904-3951
[5]   Nitrogen-Doped Carbon Nanocages as Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction [J].
Chen, Sheng ;
Bi, Jiyu ;
Zhao, Yu ;
Yang, Lijun ;
Zhang, Chen ;
Ma, Yanwen ;
Wu, Qiang ;
Wang, Xizhang ;
Hu, Zheng .
ADVANCED MATERIALS, 2012, 24 (41) :5593-5597
[6]   A review on non-precious metal electrocatalysts for PEM fuel cells [J].
Chen, Zhongwei ;
Higgins, Drew ;
Yu, Aiping ;
Zhang, Lei ;
Zhang, Jiujun .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) :3167-3192
[7]   Electrocatalyst approaches and challenges for automotive fuel cells [J].
Debe, Mark K. .
NATURE, 2012, 486 (7401) :43-51
[8]   Iron Encapsulated within Pod-like Carbon Nanotubes for Oxygen Reduction Reaction [J].
Deng, Dehui ;
Yu, Liang ;
Chen, Xiaoqi ;
Wang, Guoxiong ;
Jin, Li ;
Pan, Xiulian ;
Deng, Jiao ;
Sun, Gongquan ;
Bao, Xinhe .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (01) :371-375
[9]   Oxygen reduction catalysts for polymer electrolyte fuel cells from the pyrolysis of FeII acetate adsorbed 3,4,9,10-perylenetetracarboxylic dianhydride [J].
Faubert, G ;
Côté, R ;
Dodelet, JP ;
Lefèvre, M ;
Bertrand, P .
ELECTROCHIMICA ACTA, 1999, 44 (15) :2589-2603
[10]   Multitechnique Characterization of a Polyaniline-Iron-Carbon Oxygen Reduction Catalyst [J].
Ferrandon, Magali ;
Kropf, A. Jeremy ;
Myers, Deborah J. ;
Artyushkova, Kateryna ;
Kramm, Ulrike ;
Bogdanoff, Peter ;
Wu, Gang ;
Johnston, Christina M. ;
Zelenay, Piotr .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (30) :16001-16013
1234