Multiresponsive Block Copolymer-Modified "Hairy" Gold Nanoparticles for Remote Control of Interfaces

被引：15
|
作者：
Shi, Yelu [1 ]
Selin, Victor [1 ]
Wang, Yuhao [1 ]
Sukhishvili, Svetlana A. [1 ]
机构：
[1] Stevens Inst Technol, Dept Chem, Hoboken, NJ 07030 USA
来源：
PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION | 2013年 / 30卷 / 11期
基金：
美国国家科学基金会;
关键词：
TRANSFER RADICAL POLYMERIZATION; WEAK POLYELECTROLYTE BRUSHES; SURFACE REVERSIBLE ADDITION; SILICA NANOPARTICLES; CONTROLLED GROWTH; MIXED BRUSHES; PH; POLYMERS; BEHAVIOR;
D O I：
10.1002/ppsc.201300220
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Hybrid gold nanoparticles modified with poly(N-isopropylacrylamide)-block- poly(2-succinyloxyethyl methacrylate) (PNIPAM-b-PSEMA) brushes are synthesized using surface-initiated atom transfer radical polymerization (SI-ATRP). The "hairy" particles demonstrate reversible pH- and temperature- controlled changes in size and aggregation state in solution. When adsorbed within a sub-monolayer at a solid surface, they support reversible changes in surface wettability in response to changes in solution pH, temperature, or illumination by laser light. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：950 / 957
页数：8
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