Synthesis, characterization and crystal structure of holmium complex with β-alanine

被引：0
|
作者：
Ma, LF [1 ]
Wang, LY
Liang, FP
机构：
[1] Luoyang Teachers Coll, Dept Chem, Luoyang 471022, Peoples R China
[2] Guangxi Normal Univ, Dept Chem, Guilin 541004, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2004年 / 23卷 / 02期
关键词：
holmium complex; beta-alanine; crystal structure;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complex {[HO2(beta-ala)(6)(H2O)(4)](ClO4)(6).H2O}(n) (beta-ala = beta-alanine) has been synthesized in an aqueous solution with the pH value of 3.5. Its crystal structure was determined by X-ray diffraction method. The crystal is of triclinic, space group P (1) over bar with a = 9.1 99(2), b = 12.870(2), c = 21.620(5) Angstrom, alpha 76.92(1), beta = 81.15(1), gamma = 82.91(1)degrees, V = 2453.2(8) Angstrom(3), Z = 2 and D-c = 2.097 g/cm(3). The structure of the complex can be viewed as a one-dimensional infinite chain. The holmium, ion. is nine-coordinated with a geometry of distorted mono capped square antiprism..
引用
收藏
页码：207 / 212
页数：6
相关论文
共 50 条
  • [41] Synthesis, characterization,crystal structure and kinetics of thermal decomposition of Zn(II) complex
    Zhao, GL
    Feng, YL
    Liu, XH
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2005, 21 (04) : 598 - 602
  • [42] Synthesis, characterization and crystal structure of a novel dinuclear copper(II) coordination complex
    Gao, Jian-Gang, 1600, Chinese Ceramic Society (43):
  • [43] A ternary tetracoordinated PdII complex with metformin and dipicolinate: Synthesis, characterization and crystal structure
    Moghimi, A.
    Khavassi, H. R.
    Dashtestani, F.
    Kordestani, D.
    Jafari, A. Ekram
    Maddah, B.
    Moosavi, S. M.
    JOURNAL OF MOLECULAR STRUCTURE, 2011, 996 (1-3) : 38 - 41
  • [44] Synthesis, Characterization and Crystal Structure of a Trinuclear Diorganotin(IV) Complex with N′-acetylsalicylhydrazide
    Cui Ji-Chun
    Qiao Yan-Ling
    Ding Long-Hua
    Yin Han-Dong
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (12) : 1784 - 1787
  • [45] Synthesis, crystal structure, and characterization of a cadmium(II) complex containing an octacarboxylate ligand
    Su, Jian
    Yao, Liu-Di
    Zhang, Jun
    Wang, Xiu-Fang
    Zou, Xue-Juan
    Zhang, Sheng-Yi
    Wu, Jie-Ying
    Tian, Yu-Peng
    JOURNAL OF COORDINATION CHEMISTRY, 2015, 68 (11) : 1926 - 1935
  • [46] SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURE OF A POLYMERIC SILVER(I) COMPLEX WITH CYTOTOXIC PROPERTY
    Li, Gang-Sen
    Zhang, Hua-Lin
    JOURNAL OF THE CHILEAN CHEMICAL SOCIETY, 2015, 60 (04): : 2677 - 2680
  • [47] THE CHARACTERIZATION OF ALUMINUM - ALANINE COMPLEX
    RAO, KSJ
    RAO, GV
    MOLECULAR AND CELLULAR BIOCHEMISTRY, 1994, 137 (01) : 61 - 64
  • [48] Novel Synthesis and Crystal Structure Analysis of rac-β-(Trimethylsilyl)alanine
    Falgner, Steffen
    Schmidt, David
    Bertermann, Ruediger
    Burschka, Christian
    Tacke, Reinhold
    ORGANOMETALLICS, 2009, 28 (09) : 2927 - 2930
  • [49] Synthesis, Characterization, and Crystal Structure of a Metallamacrocycle
    Zhang, Dingjun
    Chen, Yuxian
    Zhao, Qiang
    Wu, Youzhi
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2011, 637 (09): : 1175 - 1177
  • [50] Synthesis, Characterization and Crystal Structure of Chlorodibenzyltin(IV) Complex with Dithiomorpholinocarba-mate Ligand
    尹汉东
    王传华
    马春林
    王勇
    Chinese Journal of Chemistry, 2002, (09) : 913 - 916
12345