Shapes of undecanuclear clusters and undecacoordinated metal complexes

被引:2
|
作者
Alvarez, Santiago [1 ,2 ]
机构
[1] Univ Barcelona, Dept Quim Inorgan & Organ, Seccio Quim Inorgan, Barcelona, Spain
[2] Univ Barcelona, Inst Quim Teor & Computac IQTC UB, Barcelona, Spain
关键词
Continuous shape measures; stereochemistry; transition metals; lanthanides; clusters; supramolecular architectures; coordination compounds; TRIGONAL-PRISMATIC GEOMETRY; RHODIUM CARBONYL CLUSTER; CRYSTAL-STRUCTURE; PHOTOPHYSICAL PROPERTIES; POLYOXOMETALATE CHAINS; LANTHANIDE COMPLEXES; CHEMISTRY; LIGANDS; K8IN11-TYPE; DIFFRACTION;
D O I
10.1080/00958972.2018.1442003
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The structures of molecules that arrange eleven identical atoms in one, two or three dimensions are analyzed by means of continuous shape measures. In the case of 3-D molecules, they comprise metallic clusters, boranes, supramolecular architectures, and metal coordination spheres, examples of eight different polyhedra have been identified, and in some cases, also structures that fall along the minimal interconversion pathway between two such polyhedra are discussed. [GRAPHICS] .
引用
收藏
页码:590 / 600
页数:11
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