Determination of the microscopic rate constants for the hydrolysis of diuron in soil/water mixture

被引：11

作者：

Salvestrini, S ^{[1
]}

Coppola, E ^{[1
]}

Capasso, S ^{[1
]}

机构：

[1] Univ Naples 2, Dipartimento Sci Ambientali, I-81100 Caserta, Italy

来源：

CHEMOSPHERE | 2004年 / 55卷 / 03期

关键词：

kinetic equation; hydrolysis; soil catalytic capacity; diuron; phenylureas;

D O I：

10.1016/j.chemosphere.2003.11.004

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

A kinetic equation for the analysis of the degradation reaction of xenobiotic molecules in the soil/water mixture has been derived. By means of this equation we have evaluated the microscopic rate constant for the abiotic hydrolysis of the herbicide diuron in the water phase of a soil/water mixture assuming that the reaction occurs only in the water phase and that diuron is reversibly adsorbed by the soil with a higher rate. The soil catalytic capacity on the hydrolysis of diuron was evaluated. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：333 / 337

页数：5

共 50 条

[21] Determination of microscopic rate constants for CO binding and migration in myoglobin encapsulated in silica gels
Sottini, S
Abbruzzetti, S
Viappiani, C
Ronda, L
Mozzarelli, A
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (41): : 19523 - 19528
[22] Demasking rate constants for tryptic hydrolysis of β-casein
Vorob'ev, M. M.
Vogel, V.
Maentele, W.
INTERNATIONAL DAIRY JOURNAL, 2013, 30 (01) : 33 - 38
[23] DETERMINATION OF SOME RATE CONSTANTS FOR RADICAL PROCESSES IN RADIATION CHEMISTRY OF WATER
SCHWARZ, HA
JOURNAL OF PHYSICAL CHEMISTRY, 1962, 66 (02): : 255 - &
[24] Biochar Increases Diuron Sorption and Reduces the Potential Contamination of Subsurface Water with Diuron in a Sandy Soil
Petter, Fabiano A.
Ferreira, Tamara S.
Sinhorin, Adilson P.
Lima, Larissa B.
Almeida, Fernandes A.
Pacheco, Leandro P.
Silva, Alexandre F.
PEDOSPHERE, 2019, 29 (06) : 801 - 809
[25] Sensitive determination of diuron on zinc oxide nanoparticles modified carbon paste electrode in soil and water samples
Ouedraogo, Bibata
Tall, Amidou
Bako, Yibor Fabrice Roland
Tapsoba, Issa
ELECTROANALYSIS, 2023, 35 (10)
[26] Determination of reaction mechanism and rate constants of alkaline hydrolysis of phenyl benzoate in ethanol-water medium by nonlinear least squares regression
Zhao, Yi
Wang, Guan
Li, Wei
Zhu, Zhong-liang
CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS, 2006, 82 (1-2) : 193 - 199
[27] Biochar Increases Diuron Sorption and Reduces the Potential Contamination of Subsurface Water with Diuron in a Sandy Soil
Fabiano A.PETTER
Tamara S.FERREIRA
Adilson P.SINHORIN
Larissa B.LIMA
Fernandes A.ALMEIDA
Leandro P.PACHECO
Alexandre F.SILVA
Pedosphere, 2019, 29 (06) : 801 - 809
[28] DETERMINATION OF KINETIC CONSTANTS IN THE ARSENIC TRICHLORIDE HYDROLYSIS
DIOGIDZE, OS
BESSARABOV, AM
ALLAKHVERDOV, GR
EFREMOV, AA
GRINBERG, EE
EFREMOV, VA
ZHURNAL FIZICHESKOI KHIMII, 1986, 60 (04): : 1025 - 1027
[29] EXPERIMENTAL DETERMINATION OF POLYVALENT ELEMENT CONSTANTS IN HYDROLYSIS
DAVYDOV, YP
DOKLADY AKADEMII NAUK BELARUSI, 1972, 16 (07): : 620 - &
[30] DETERMINATION OF RATE CONSTANTS OF HYDROLYSIS BY A DISTRIBUTION TECHNIQUE AND ITS APPLICATION TO ISOPROPOXYMETHYL-PHOSPHORYL CHLORIDE
LARSSON, L
ACTA CHEMICA SCANDINAVICA, 1958, 12 (02): : 303 - 307

← 1 2 3 4 5 →