Single-crystal polythiophene microwires grown by self-assembly

被引:268
作者
Kim, DH [1 ]
Han, JT [1 ]
Park, YD [1 ]
Jang, Y [1 ]
Cho, JH [1 ]
Hwang, M [1 ]
Cho, K [1 ]
机构
[1] Pohang Univ Sci & Technol, Dept Chem Engn, Pohang 790784, South Korea
关键词
D O I
10.1002/adma.200502442
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Single-crystal polythiophene microwires with unprecedented electrical characteristics such as low resistance (0.5 M Omega), a channel current as high as 25 mu A, and well-resolved gate modulation (see figure) have been obtained by specific control over the supramolecular organization of individual polymer chains, which show preferential well-ordered interchain stacking along the wire axis. This approach offers a promising protocol for new flexible electronics.
引用
收藏
页码:719 / +
页数:6
相关论文
共 32 条
[1]   Mobility studies of field-effect transistor structures based on anthracene single crystals [J].
Aleshin, AN ;
Lee, JY ;
Chu, SW ;
Kim, JS ;
Park, YW .
APPLIED PHYSICS LETTERS, 2004, 84 (26) :5383-5385
[2]   Functionalized pentacene: Improved electronic properties from control of solid-state order [J].
Anthony, JE ;
Brooks, JS ;
Eaton, DL ;
Parkin, SR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (38) :9482-9483
[3]   Soluble and processable regioregular poly(3-hexylthiophene) for thin film field-effect transistor applications with high mobility [J].
Bao, Z ;
Dodabalapur, A ;
Lovinger, AJ .
APPLIED PHYSICS LETTERS, 1996, 69 (26) :4108-4110
[4]   Suppression of charge carrier tunneling through organic self-assembled monolayers [J].
Boulas, C ;
Davidovits, JV ;
Rondelez, F ;
Vuillaume, D .
PHYSICAL REVIEW LETTERS, 1996, 76 (25) :4797-4800
[5]   LOGIC GATES MADE FROM POLYMER TRANSISTORS AND THEIR USE IN RING OSCILLATORS [J].
BROWN, AR ;
POMP, A ;
HART, CM ;
DELEEUW, DM .
SCIENCE, 1995, 270 (5238) :972-974
[6]   Highly ordered structures of amphiphilic polythiophenes in aqueous media [J].
Brustolin, F ;
Goldoni, F ;
Meijer, EW ;
Sommerdijk, NAJM .
MACROMOLECULES, 2002, 35 (03) :1054-1059
[7]   Low-voltage, 30 nm channel length, organic transistors with a self-assembled monolayer as gate insulating films [J].
Collet, J ;
Tharaud, O ;
Chapoton, A ;
Vuillaume, D .
APPLIED PHYSICS LETTERS, 2000, 76 (14) :1941-1943
[8]   Large-scale complementary integrated circuits based on organic transistors [J].
Crone, B ;
Dodabalapur, A ;
Lin, YY ;
Filas, RW ;
Bao, Z ;
LaDuca, A ;
Sarpeshkar, R ;
Katz, HE ;
Li, W .
NATURE, 2000, 403 (6769) :521-523
[9]   Organic oscillator and adaptive amplifier circuits for chemical vapor sensing [J].
Crone, BK ;
Dodabalapur, A ;
Sarpeshkar, R ;
Gelperin, A ;
Katz, HE ;
Bao, Z .
JOURNAL OF APPLIED PHYSICS, 2002, 91 (12) :10140-10146
[10]   Organic single-crystal field-effect transistors [J].
de Boer, RWI ;
Gershenson, ME ;
Morpurgo, AF ;
Podzorov, V .
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2004, 201 (06) :1302-1331