Efficient Catalytic Hydrogenation of Butyl Levulinate to γ-Valerolactone over a Stable and Magnetic CuNiCoB Amorphous Alloy Catalyst

被引:22
作者
Chen, Bo [1 ]
Guo, Haijun [2 ,3 ,4 ]
Wan, Zhe [1 ]
Xu, Xiaocheng [1 ]
Zhang, Hairong [2 ,3 ,4 ]
Zhao, Dan [1 ]
Chen, Xinde [2 ,3 ,4 ]
Zhang, Ning [1 ]
机构
[1] Nanchang Univ, Coll Chem, Inst Appl Chem, 999 Xuefu Rd, Nanchang 330031, Jiangxi, Peoples R China
[2] Chinese Acad Sci, Guangzhou Inst Energy Convers, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China
[3] CAS Key Lab Renewable Energy, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China
[4] Guangdong Prov Key Lab New & Renewable Energy Res, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
SUPPORTED RUTHENIUM CATALYSTS; LIQUID-PHASE HYDROGENATION; FURFURYL ALCOHOL; NI-B; SELECTIVE HYDROGENATION; BIMETALLIC CATALYSTS; ETHYL LEVULINATE; ACID; BIOMASS; CONVERSION;
D O I
10.1021/acs.energyfuels.8b00378
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
A series of low-cost, magnetic, and high-efficiency CuNiCoB amorphous alloy catalysts were developed by the chemical reduction method for selective hydrogenation of butyl levulinate (BL) to gamma-valerolactone (GVL). The catalysts were characterized by inductively coupled plasma optical emission spectrometry, Brunauer-Emmett-Teller, X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and hydrogen temperature-programmed desorption techniques. The results indicated that the CuNiCoB amorphous alloy nanosheets with well-dispersed Cu nanoparticles played an important role in enhancing the hydrogenation activity. The reaction temperature, pressure, time, and substrate concentration were optimized. The maximum GVL yield of 89.5% with BL conversion of 99.7% was achieved over the best Cu0.5Ni1Co3B catalyst using 3 wt % dosage relative to BL at 473 K under 3.0 MPa H-2 after 3 h. The considerable stability of Cu0.5Ni1Co3B during catalytic recovery and reuse experiments (5 cycles) was exhibited as a result of the transformation of CuNiCoB amorphous alloy active sites to a Cu-Ni-Co ternary alloy. The stable and magnetic catalyst was demonstrated to be a promising candidate to produce more value-added compounds from biomass-derived raw materials.
引用
收藏
页码:5527 / 5535
页数:9
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