3d and 4d coordination complexes and coordination polymers involving electroactive tetrathiafulvalene containing ligands

被引：6

作者：

Pointillart, Fabrice ^{[1
]}

Golhen, Stephane ^{[1
]}

Cador, Olivier ^{[1
]}

Ouahab, Lahcene ^{[1
]}

机构：

[1] Univ Rennes 1, Inst Sci Chim Rennes, UMR CNRS 6226, F-35042 Rennes, France

来源：

COMPTES RENDUS CHIMIE | 2013年 / 16卷 / 07期

关键词：

Coordination complexes; Coordination polymers; Electroactive ligands; Tetrathiafulvalene; TRANSITION-METAL-COMPLEXES; REDOX-ACTIVE LIGAND; RADICAL-CATION SALT; CRYSTAL-STRUCTURE; CHARGE-TRANSFER; CU-II; MOLECULAR CONSTITUENTS; ORGANIC CONDUCTORS; COPPER-COMPLEXES; TTF DERIVATIVES;

D O I：

10.1016/j.crci.2012.11.016

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The "through bond" approach has been recently developed to increase the interaction between the mobile pi and localized d electrons in multifunctional molecular materials involving tetrathiafulvalene-based ligands. This article reviews the 3d and 4d coordination complexes and polymers elaborated from a library of tetrathiafulvalene derivatives containing ligands obtained recently in our group. The different synthetic ways of the complexes are highlighted as well as their chemical and physical properties. (C) 2012 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.

引用

页码：679 / 687

页数：9

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