Mn-Based tin sulfide Sr3MnSn2S8 with a wide band gap and strong nonlinear optical response

被引：28
|
作者：
Liu, Chuang [1 ]
Mei, Dajiang [1 ]
Cao, Wangzhu [1 ]
Yang, Yi [2 ,3 ]
Wu, Yuandong [1 ]
Li, Guobao [4 ]
Lin, Zheshuai [2 ,3 ]
机构：
[1] Shanghai Univ Engn Sci, Coll Chem & Chem Engn, Shanghai 201620, Peoples R China
[2] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China
[3] Univ Chinese Acad Sci, Beijing 100190, Peoples R China
[4] Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY C | 2019年 / 7卷 / 05期
基金：
中国国家自然科学基金;
关键词：
2ND-HARMONIC GENERATION RESPONSE; BOND-VALENCE PARAMETERS; LASER DAMAGE THRESHOLD; CRYSTAL-STRUCTURES; M-IV; GE; SN; PERFORMANCES; SI; CHALCOGENIDES;
D O I：
10.1039/c8tc05904g
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A new quaternary Sn-containing sulfide (Sr3MnSn2S8) was synthesized using a traditional high temperature solid-state method. It crystallizes in the space group I43d with a = 14.2287(6) angstrom and Z = 8. Direct extrapolation using the upper tangent revealed an energy band gap at 3.02 eV, larger than that of AgGaS2 at 2.65 eV. Sr3MnSn2S8 exhibited a strong second harmonic generation response, almost equivalent to that of the benchmark AgGaS2, and its laser damage threshold was about 3 times that of AgGaS2.
引用
收藏
页码：1146 / 1150
页数：5
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