Preparation of Cu2ZnSnS4 film by sulfurizing solution deposited precursors

被引：23
作者：
Gao, Chao [1 ]
Shen, Honglie [1 ]
Jiang, Feng [1 ]
Guan, Hao [1 ]
机构：
[1] Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Technol, Nanjing 210016, Jiangsu, Peoples R China
来源：
APPLIED SURFACE SCIENCE | 2012年 / 261卷
基金：
美国国家科学基金会;
关键词：
Cu2ZnSnS4; Thin film; Low cost method; Solution deposited precursor; SOLAR-CELLS; THIN-FILMS; NANOCRYSTALS; BINARY; LAYER;
D O I：
10.1016/j.apsusc.2012.07.137
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Cu2ZnSnS4 (CZTS) film was obtained by sulfurizing (Cu, Sn)S/ZnS structured precursor that was prepared by a combination of the successive ionic layer adsorption and reaction method and the chemical bath deposition method. Pure Cu2ZnSnS4 phase was obtained when the precursor was annealed at 500 degrees C for 2 h. The structure, composition, morphology and optical properties of the CZTS film were studied. The results show that the CZTS film has a relatively compact morphology, and the composition of the film is close to the stoichiometric ratio of Cu2ZnSnS4. The film presents a large optical absorption coefficient (larger than 10(4) cm(-1) when the photo energy is beyond 1.47 eV). The optical band-gap of the film is around 1.56 eV. This method is considered a potential way to prepare high quality CZTS film. (C) 2012 Elsevier B. V. All rights reserved.
引用
收藏
页码：189 / 192
页数：4
相关论文
共 50 条
  • [21] Pre-annealing of precursors of Cu2ZnSnS4 thin films prepared by sol-gel sulfurizing method
    Tanaka, Kunihiko
    Moritake, Noriko
    Oonuki, Masatoshi
    Uchiki, Hisao
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS, 2008, 47 (01) : 598 - 601
  • [22] EFFECT OF TIN PRECURSORS ON THE DEPOSITION OF Cu2ZnSnS4 THIN FILMS
    Nagamalleswari, D.
    Kishorekumar, Y. B.
    Kiran, Y. B.
    Sureshbabu, G.
    [J]. CHALCOGENIDE LETTERS, 2020, 17 (10): : 505 - 513
  • [23] Liquefied petroleum gas (LPG) sensing using spray deposited Cu2ZnSnS4 thin film
    Patil, S. J.
    Bulakhe, R. N.
    Lokhande, C. D.
    [J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2016, 117 : 310 - 316
  • [24] Preparation and photoelectrochemical properties of densely immobilized Cu2ZnSnS4 nanoparticle films
    Kameyama, Tatsuya
    Osaki, Takaaki
    Okazaki, Ken-ichi
    Shibayama, Tamaki
    Kudo, Akihiko
    Kuwabata, Susumu
    Torimoto, Tsukasa
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (25) : 5319 - 5324
  • [25] Preparation and characterization of Cu2ZnSnS4 microparticles via a facile solution route
    Zhou, Jicheng
    You, Liang
    Li, Shaowen
    Yang, Yanlin
    [J]. MATERIALS LETTERS, 2012, 81 : 248 - 250
  • [26] Phases formation of Cu2ZnSnS4 thin films by sulfurizing stacked precursors by sputtering from Cu-Zn and Cu-Sn targets
    Sun, Rujun
    Zhuang, Daming
    Zhao, Ming
    Zhang, Ning
    Xie, Min
    Wei, Yaowei
    Ren, Guoan
    Wu, Yixuan
    Gong, Qianming
    Wei, Jinquan
    [J]. THIN SOLID FILMS, 2019, 690
  • [27] Fabrication of CU2ZnSnS4 thin film by sulfurization of stacked solution-based precursors with different copper sources
    Kao, Chia-Yu
    Shen, Pin-Chun
    Ku, Chun-Wei
    Lan, Shiang
    Lin, Ming-Shiun
    Lin, Ching-Fuh
    [J]. 2012 12TH IEEE CONFERENCE ON NANOTECHNOLOGY (IEEE-NANO), 2012,
  • [28] Cu2ZnSnS4 solar cells grown by sulphurisation of sputtered metal precursors
    Marchionna, S.
    Garattini, P.
    Le Donne, A.
    Acciarri, M.
    Tombolato, S.
    Binetti, S.
    [J]. THIN SOLID FILMS, 2013, 542 : 114 - 118
  • [29] Cu2ZnSnS4 thin film solar cells
    Katagiri, H
    [J]. THIN SOLID FILMS, 2005, 480 : 426 - 432
  • [30] Comparative study of Cu2ZnSnS4 film growth
    Yoo, Hyesun
    Kim, JunHo
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2011, 95 (01) : 239 - 244
12345