A new biogenerated Rh-based catalyst for aqueous biphasic hydroformylation

被引：8
|
作者：
Paganelli, Stefano [1 ]
Piccolo, Oreste [2 ]
Baldi, Franco [1 ]
Gallo, Michele [1 ]
Tassini, Riccardo [1 ]
Rancan, Marzio [3 ,4 ]
Armelao, Lidia [3 ,4 ]
机构：
[1] Univ Ca Foscari Venezia, Dipartimento Sci Mol & Nanosistemi, I-30170 Venice, Italy
[2] SCSOP, I-23896 Sirtori, LC, Italy
[3] Univ Padua, Dipartimento Sci Chim, I-35131 Padua, Italy
[4] Univ Padua, CNR, IENI, I-35131 Padua, Italy
来源：
CATALYSIS COMMUNICATIONS | 2015年 / 71卷
关键词：
Rhodium; Biphasic hydroformylation; Catalyst; Klebsiella oxytoca; Polysaccharide; SUPPORTED PALLADIUM(0) CATALYST; COMPLEXES; BIOPOLYMER; CHITOSAN; GROWTH;
D O I：
10.1016/j.catcom.2015.08.001
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new bio-generated rhodium based system embedded in a peculiar polysaccharide matrix (Rh-EPS), was obtained and purified from cultures of bacterial cells of Klebsiella oxytoca DSM 29614. The product was analyzed with different techniques to obtain information on its structure-property correlation. In order to determine its catalytic activity and selectivity in the aqueous biphasic hydroformylation some olefins were chosen as model substrates, obtaining fine-good results. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：32 / 36
页数：5
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