Low-Threshold Photon Upconversion Capsules Obtained by Photoinduced Interfacial Polymerization

被引:65
作者
Kang, Ji-Hwan [1 ]
Reichmanis, Elsa [1 ,2 ]
机构
[1] Georgia Inst Technol, Sch Chem & Biomol Engn, Atlanta, GA 30332 USA
[2] Georgia Inst Technol, Sch Mat Sci & Engn, Sch Chem & Biochem, Atlanta, GA 30332 USA
关键词
luminescence; microcapsules; photochemistry; triplet-triplet annihilation; upconversion; LOW-POWER; SOLAR-CELLS; QUANTUM YIELDS; VISIBLE-LIGHT; IN-VIVO; NANOPARTICLES; EXCITATION; EFFICIENCY; CRYSTALS;
D O I
10.1002/anie.201205540
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nonlinear optics: Photoinduced interfacial polymerization within a microfluidic channel is shown to be an effective method to prepare microcapsules that provide for photon upconversion by triplet-triplet annihilation (see picture). In this approach, an elastomeric shell formed on the inner surface of the microcapsules served as an efficient protective shield, whereas a liquid core promoted the required energy transfer for the upconverted luminescence. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:11841 / 11844
页数:4
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