The weakly-bound complex Cl•N2O studied by high resolution photodetachment photoelectron spectroscopy

被引：1
作者：
Boesl, Ulrich [1 ]
Distelrath, Volker [1 ]
Selzle, Heinrich [1 ]
机构：
[1] Tech Univ Munich, Dept Chem, D-85747 Garching, Germany
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2008年 / 10卷 / 41期
关键词：
D O I：
10.1039/b807992g
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Zero kinetic energy photoelectron spectroscopy of the weakly bound complex Cl-center dot N2O is presented. Adiabatic detachment energies between the anionic complex and the neutral complex states X-1/2, I-3/2, and II1/2 as well as frequencies of van der Waals modes are supplied. Supported by theoretical simulations, these results correlate with a T-shaped structure of the anionic and an L-shaped structure of the neutral molecular complex. The weakly bound neutral complex Cl center dot N2O has been discussed as a prereactive state of the chemical reaction Cl + N2O -> ClO + N-2 [A. Lesar, M. Hodoscek, M. Senegacnik, J. Chem. Phys. 1996, 105, 917].
引用
收藏
页码：6252 / 6257
页数：6
相关论文
共 35 条
  • [1] STUDY OF HALOGEN CARBON-DIOXIDE CLUSTERS AND THE FLUOROFORMYLOXYL RADICAL BY PHOTODETACHMENT OF X(-)(CO2) (X=I,CL,BR) AND FCO2-
    ARNOLD, DW
    BRADFORTH, SE
    KIM, EH
    NEUMARK, DM
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1995, 102 (09) : 3493 - 3509
  • [2] STUDY OF I-(CO2)N, BR-(CO2)N, AND I-(N2O)N CLUSTERS BY ANION PHOTOELECTRON-SPECTROSCOPY
    ARNOLD, DW
    BRADFORTH, SE
    KIM, EH
    NEUMARK, DM
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1995, 102 (09) : 3510 - 3518
  • [3] THE QUADRUPOLE-MOMENTS OF CARBON-DIOXIDE AND CARBON-DISULFIDE
    BATTAGLIA, MR
    BUCKINGHAM, AD
    NEUMARK, DM
    PIERENS, RK
    WILLIAMS, JH
    [J]. MOLECULAR PHYSICS, 1981, 43 (05) : 1015 - 1020
  • [4] ISOTOPE SHIFT IN THE ELECTRON-AFFINITY OF CHLORINE
    BERZINSH, U
    GUSTAFSSON, M
    HANSTORP, D
    KLINKMULLER, A
    LJUNGBLAD, U
    MARTENSSONPENDRILL, AM
    [J]. PHYSICAL REVIEW A, 1995, 51 (01): : 231 - 238
  • [5] Boesl U, 1999, AD SE PH CH, V10A-1, P809
  • [6] Time-of-flight mass analyser for anion mass spectrometry and anion photoelectron spectroscopy
    Boesl, U
    Bässmann, C
    Käsmeier, R
    [J]. INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2001, 206 (03) : 231 - 244
  • [7] Laser-based ion source for mass spectrometry and laser spectroscopy of negative ions
    Boesl, U
    Bässmann, C
    Drechsler, G
    Distelrath, V
    [J]. EUROPEAN MASS SPECTROMETRY, 1999, 5 (06): : 455 - 470
  • [8] BOHMER E, 1992, J CHEM PHYS, V97, P2536, DOI 10.1063/1.463092
  • [9] ELECTRIC FIELD-GRADIENT-INDUCED BIREFRINGENCE IN N-2, C2H6, C3H6, CL-2, N2O AND CH3F
    BUCKINGHAM, AD
    GRAHAM, C
    WILLIAMS, JH
    [J]. MOLECULAR PHYSICS, 1983, 49 (03) : 703 - 710
  • [10] Structure and dynamics of I2-(N2O)n:: Monte Carlo and molecular dynamics simulations
    Cho, E
    Shin, S
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2001, 115 (14) : 6376 - 6384
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