Relationship of the Permittivity with the Activity Coefficients of Water and Ions in Aqueous Solutions of Lithium and Sodium Sulfates

被引:8
作者
Shilov, I. Yu. [1 ]
Lyashchenko, A. K. [2 ]
机构
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
[2] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
基金
俄罗斯基础研究基金会;
关键词
electrolyte solutions; ion pairs; hydration; ALKALI-METAL SULFATES; ASSOCIATION; LI2SO4; THERMODYNAMICS; TEMPERATURE; RELAXATION; SOLVATION; HYDRATION; NITRATES; DYNAMICS;
D O I
10.1134/S003602362008015X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The activity coefficients in aqueous solutions of lithium and sodium sulfates at 298 K were calculated by the generalized Debye-Huckel theory using the experimental values of the static permittivity of the solutions. The effect of the hydration and ion association on the dielectric and thermodynamic properties of the electrolyte solutions was considered.
引用
收藏
页码:1240 / 1244
页数:5
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