Porous phosphorus-based element organic frameworks: A new platform for transition metal catalysts immobilization

被引：33

作者：

Fritsch, Julia ^{[1
]}

Drache, Franziska ^{[1
]}

Nickerl, Georg ^{[1
]}

Boehlmann, Winfried ^{[2
]}

Kaskel, Stefan ^{[1
]}

机构：

[1] Tech Univ Dresden, Dept Inorgan Chem, D-01069 Dresden, Germany

[2] Univ Leipzig, Fac Phys & Earth Sci, D-04103 Leipzig, Germany

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2013年 / 172卷

关键词：

Element organic framework (EOF); Phosphorus; Transition metals; Wilkinson; Catalysis; PERMANENT POROSITY; SURFACE-AREA; NETWORKS; POLYMERS;

D O I：

10.1016/j.micromeso.2012.12.049

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

EOF-17 (EOF: element organic framework) represents a new member of the EOF family based on phosphorus connected via an organic biphenyl. It is characterized by a specific surface area (BET) of up to 646 m(2)/g and a thermal stability of up to 360 degrees C. As a heterogeneous analog of PPh3 the permanent infiltration of rhodium and palladium complexes is demonstrated. EOF-17 infiltrated with rhodium was successfully tested in the transfer hydrogenation of cyclohexanone. (C) 2013 Elsevier Inc. All rights reserved,

引用

页码：167 / 173

页数：7

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