Hydrothermal carbonization of lignocellulosic biomass

被引:342
作者
Xiao, Ling-Ping [1 ]
Shi, Zheng-Jun [1 ]
Xu, Feng [1 ]
Sun, Run-Cang [1 ,2 ]
机构
[1] Beijing Forestry Univ, Inst Biomass Chem & Technol, Beijing 100083, Peoples R China
[2] S China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
Hydrothermal carbonization; Biomass; Phenolic compound; XPS; GC-MS; CARBON; MONOSACCHARIDES;
D O I
10.1016/j.biortech.2012.05.060
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Hydrothermal carbonization (HTC) is a novel thermochemical conversion process to convert lignocellulosic biomass into value-added products. HTC processes were studied using two different biomass feed-stocks: corn stalk and Tamarix ramosissima. The treatment brought an increase of the higher heating values up to 29.2 and 28.4 MJ/kg for corn stalk and T. ramosissima, respectively, corresponding to an increase of 66.8% and 58.3% as compared to those for the raw materials. The resulting lignite-like solid products contained mainly lignin with a high degree of aromatization and a large amount of oxygen-containing groups. Liquid products extracted with ethyl acetate were analyzed by gas chromatography mass spectrometry. The identified degradation products were phenolic compounds and furan derivatives, which may be desirable feedstocks for biodiesel and chemical production. Based on these results, HTC is considered to be a potential treatment in a lignocellulosic biomass refinery. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:619 / 623
页数:5
相关论文
共 14 条
[1]   Hydrothermal Carbonization-1. Influence of Lignin in Lignocelluloses [J].
Dinjus, Eckhard ;
Kruse, Andrea ;
Troeger, Nicole .
CHEMICAL ENGINEERING & TECHNOLOGY, 2011, 34 (12) :2037-2043
[2]   Hydrothermal carbonization of biomass: A summary and discussion of chemical mechanisms for process engineering [J].
Funke, Axel ;
Ziegler, Felix .
BIOFUELS BIOPRODUCTS & BIOREFINING-BIOFPR, 2010, 4 (02) :160-177
[3]   Hydrothermal processing of lignocellulosic materials [J].
Garrote, G ;
Domínguez, H ;
Parajó, JC .
HOLZ ALS ROH-UND WERKSTOFF, 1999, 57 (03) :191-202
[4]   Hydrothermal Carbonization (HTC) of Lignocellulosic Biomass [J].
Hoekman, S. Kent ;
Broch, Amber ;
Robbins, Curtis .
ENERGY & FUELS, 2011, 25 (04) :1802-1810
[5]   Depolymerization of steam-treated lignin for the production of green chemicals [J].
Lavoie, Jean-Michel ;
Bare, Wadou ;
Bilodeau, Mathieu .
BIORESOURCE TECHNOLOGY, 2011, 102 (07) :4917-4920
[6]   Hydrothermal carbonization of biomass residuals: a comparative review of the chemistry, processes and applications of wet and dry pyrolysis [J].
Libra, Judy A. ;
Ro, Kyoung S. ;
Kammann, Claudia ;
Funke, Axel ;
Berge, Nicole D. ;
Neubauer, York ;
Titirici, Maria-Magdalena ;
Fuehner, Christoph ;
Bens, Oliver ;
Kern, Juergen ;
Emmerich, Karl-Heinz .
BIOFUELS-UK, 2011, 2 (01) :71-106
[7]   Hydrothermal carbonization of anaerobically digested maize silage [J].
Mumme, Jan ;
Eckervogt, Lion ;
Pielert, Judith ;
Diakite, Mamadou ;
Rupp, Fabian ;
Kern, Juergen .
BIORESOURCE TECHNOLOGY, 2011, 102 (19) :9255-9260
[8]   Hydrothermal preparation of carbon microspheres from mono-saccharides and phenolic compounds [J].
Ryu, Jihye ;
Suh, Young-Woong ;
Suh, Dong Jin ;
Ahn, Dong June .
CARBON, 2010, 48 (07) :1990-1998
[9]   The production of carbon materials by hydrothermal carbonization of cellulose [J].
Sevilla, M. ;
Fuertes, A. B. .
CARBON, 2009, 47 (09) :2281-2289
[10]   Hydrothermal carbonization of biomass as a route for the sequestration of CO2: Chemical and structural properties of the carbonized products [J].
Sevilla, Marta ;
Antonio Macia-Agullo, Juan ;
Fuertes, Antonio B. .
BIOMASS & BIOENERGY, 2011, 35 (07) :3152-3159