Synthesis, structure and thermogravimetric analysis of Ni-Cd and Cu-Cd heterometallic complexes based on flexible carboxylate ligands

被引：5

作者：

Liu, Yang ^{[1
]}

Kuang, Dai-Zhi ^{[1
]}

Feng, Yong-Lan ^{[1
]}

Fu, Wei-Wei ^{[1
]}

机构：

[1] Hengyang Normal Univ, Hunan Prov Coll, Key Lab Funct Organometall Mat, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China

来源：

TRANSITION METAL CHEMISTRY | 2013年 / 38卷 / 08期

关键词：

COORDINATION POLYMERS; CRYSTAL; FRAMEWORKS; CHEMISTRY; DESIGN; IONS;

D O I：

10.1007/s11243-013-9758-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two 3d-4d heterometallic coordination polymers, namely NiCd(mal)(2)(H2O)(4) (1) and [CuCd(bicH(2))(NO3)Cl-2(H2O)]a <...H2O (2) [H(2)mal = malonic acid, bicH(3) = N,N-bis(2-hydroxyethyl) glycine], have been synthesized under mild conditions and characterized by single-crystal X-ray diffraction, elemental analysis and IR spectrophotometry. Complex 1 is a Ni-Cd heterometallic polymer with 2D extended structure bridged by the mal(2-) groups. Complex 2 displays an intriguing 3D Cu-Cd architecture and is the first 3d-4d heterometallic bicinate complex. The TG analyses of both complexes are reported.

引用

页码：849 / 853

页数：5

共 31 条

[1]

Albedyhl S, 2002, EUR J INORG CHEM, P1400

[2] Coordination chemistry of 2-hydroxymethylbenzimidazole complexes with copper(II) and cadmium(II) ions: Similarities and differences [J].

Barszcz, Barbara ;

Jablonska-Wawrzycka, Agnieszka ;

Stadnicka, Katarzyna ;

Jezierska, Julia .

POLYHEDRON, 2008, 27 (17) :3500-3508

[3] Magnetism of lanthanides in molecular materials with transition-metal ions and organic radicals [J].

Benelli, C ;

Gatteschi, D .

CHEMICAL REVIEWS, 2002, 102 (06) :2369-2387

[4] Design, chirality, and flexibility in nanoporous molecule-based materials [J].

Bradshaw, D ;

Claridge, JB ;

Cussen, EJ ;

Prior, TJ ;

Rosseinsky, MJ .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :273-282

[5] Cyano-Bridged 2D Bimetallic 4f-3d Arrays with Monolayered Stair-Like, Brick-Wall-Like, or Bilayered Topologies - Rational Syntheses and Crystal Structures [J].

Chen, Wen-Tong ;

Wu, A-Qing ;

Guo, Guo-Cong ;

Wang, Ming-Sheng ;

Cai, Li-Zhen ;

Huang, Jin-Shun .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (18) :2826-2835

[6] Syntheses, structures and photophysical properties of new heterodinuclear cd-ln coordination complexes (Ln = sm, eu, tb, nd, ho, er) [J].

Chi, Yu-Xian ;

Niu, Shu-Yun ;

Wang, Zhao-Long ;

Jin, Jing .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (14) :2336-2343

[7] A porous coordination-polymer crystal containing one-dimensional water chains exhibits guest-induced lattice distortion and a dielectric anomaly [J].

Cui, HengBo ;

Zhou, Biao ;

Long, La-Sheng ;

Okano, Yoshinori ;

Kobayashi, Hayao ;

Kobayashi, Akiko .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (18) :3376-3380

[8] Three dimensional metal-malonate frameworks with pillared layered architecture: Unusual role of metal-chelate as pillar [J].

Dey, Biswajit ;

Das, Amrita ;

Choudhury, Somnath Ray ;

Jana, Atish Dipankar ;

Lu, Li-Ping ;

Zhu, Miao-Li ;

Mukhopadhyay, Subrata .

INORGANICA CHIMICA ACTA, 2010, 363 (05) :981-987

[9]

Farrugia L. J., 1999, Journal of Applied Crystallography, V32, P837, DOI [DOI 10.1107/S0021889812029111, 10.1107/S0021889899006020, DOI 10.1107/S0021889899006020]

[10] New 3-D La(III)-Cu(II)-containing coordination polymer with a high potential porosity [J].

Guillou, Olivier ;

Daiguebonne, Carole ;

Camara, Magatte ;

Kerbellec, Nicolas .

INORGANIC CHEMISTRY, 2006, 45 (21) :8468-8470

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