Zeolites with nanometer diffusion lengths and implications in shape selective catalysis

被引:8
作者
Bhan, Aditya [1 ]
Tsapatsis, Michael [1 ]
机构
[1] Univ Minnesota, Dept Chem Engn & Mat Sci, Minneapolis, MN 55455 USA
关键词
Absolute minimum - Diffusion length - Hierarchical zeolites - Shape-selective catalysis - Sub-units - Unit cells;
D O I
10.1016/j.coche.2013.06.001
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
A long-standing synthetic challenge is to reduce the size of zeolitic domains to its absolute minimum, the unit or sub-unit cell dimension. Hierarchical zeolites with singe-unit or few-unit cell zeolite domains along with methods to assess adsorption, diffusion and reaction in these materials are reviewed.
引用
收藏
页码:320 / 324
页数:5
相关论文
共 33 条
[1]   A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].
BECK, JS ;
VARTULI, JC ;
ROTH, WJ ;
LEONOWICZ, ME ;
KRESGE, CT ;
SCHMITT, KD ;
CHU, CTW ;
OLSON, DH ;
SHEPPARD, EW ;
MCCULLEN, SB ;
HIGGINS, JB ;
SCHLENKER, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843
[2]   Specificity of sites within eight-membered ring zeolite channels for carbonylation of methyls to acetyls [J].
Bhan, Aditya ;
Allian, Ayman D. ;
Sunley, Glenn J. ;
Law, David J. ;
Iglesia, Enrique .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (16) :4919-4924
[3]   Formation of Hierarchically Organized Zeolites by Sequential Intergrowth [J].
Chaikittisilp, Watcharop ;
Suzuki, Yuki ;
Mukti, Rino R. ;
Suzuki, Tatsuya ;
Sugita, Keisuke ;
Itabashi, Keiji ;
Shimojima, Atsushi ;
Okubo, Tatsuya .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (12) :3355-3359
[4]   Hydrothermal Synthesis of Zeolites with Three-Dimensionally Ordered Mesoporous-Imprinted Structure [J].
Chen, Huiyong ;
Wydra, James ;
Zhang, Xueyi ;
Lee, Pyung-Soo ;
Wang, Zhuopeng ;
Fan, Wei ;
Tsapatsis, Michael .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (32) :12390-12393
[5]   Catalytic consequences of hydroxyl group location on the kinetics of n-hexane hydroisomerization over acidic zeolites [J].
Chiang, Hsu ;
Bhan, Aditya .
JOURNAL OF CATALYSIS, 2011, 283 (01) :98-107
[6]   Catalytic consequences of hydroxyl group location on the rate and mechanism of parallel dehydration reactions of ethanol over acidic zeolites [J].
Chiang, Hsu ;
Bhan, Aditya .
JOURNAL OF CATALYSIS, 2010, 271 (02) :251-261
[7]   Mercaptosilane-Assisted Synthesis of Metal Clusters within Zeolites and Catalytic Consequences of Encapsulation [J].
Choi, Minkee ;
Wu, Zhijie ;
Iglesia, Enrique .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (26) :9129-9137
[8]   Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts [J].
Choi, Minkee ;
Na, Kyungsu ;
Kim, Jeongnam ;
Sakamoto, Yasuhiro ;
Terasaki, Osamu ;
Ryoo, Ryong .
NATURE, 2009, 461 (7261) :246-U120
[9]   Delaminated zeolite precursors as selective acidic catalysts [J].
Corma, A ;
Fornes, V ;
Pergher, SB ;
Maesen, TLM ;
Buglass, JG .
NATURE, 1998, 396 (6709) :353-356
[10]   Characterization of the Pore Structure of Three-Dimensionally Ordered Mesoporous Carbons Using High Resolution Gas Sorption [J].
Cychosz, Katie A. ;
Guo, Xuefeng ;
Fan, Wei ;
Cimino, Richard ;
Gor, Gennady Yu. ;
Tsapatsis, Michael ;
Neimark, Alexander V. ;
Thommes, Matthias .
LANGMUIR, 2012, 28 (34) :12647-12654