Syntheses, structures and fluorescence studies of two new cadmium(II) pyridyl-diphosphonates

被引：30

作者：

Hu, Jiyong ^{[1
]}

Zhao, Jin'an ^{[1
]}

Hou, Hongwei ^{[1
]}

Fan, Yaoting ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Henan 450052, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 10期

基金：

中国国家自然科学基金;

关键词：

Pyridyl-diphosphonate; Cadmium complex; Crystal structure; Luminescence;

D O I：

10.1016/j.inoche.2008.06.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new cadmium diphosphonate complexes, namely, Cd-2(H2O)(2)[(C5H5N)CH2C(OH)(PO3)(PO3H)](2) 1 and Cd-2(H2O)(Cl)[(C5H5N)CH2C(OH)(PO3)(2)] 2, based on [1-hydroxy-2-(3-pyridyl)-ethylidenel-bis-[phosphonic acid] monosodium salt have been synthesized under hydrothermal reaction and characterized by single crystal X-ray diffraction. Both complexes show strong fluorescence emission in contrast to the free ligand, respectively, in solid state at ambient temperature. (C) 2008 Published by Elsevier B.V.

引用

页码：1110 / 1112

页数：3

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