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Promoting Effect of CeO2 on the Catalytic Activity of Rhodium Supported on Y-Stabilized ZrO2 for NO-CO-C3H6-O2 Reactions
被引:9
|作者:
Haneda, Masaaki
[1
]
Sawada, Hirotaka
[1
]
Kamiuchi, Naoto
[1
]
Ozawa, Masakuni
[1
]
机构:
[1] Nagoya Inst Technol, Adv Ceram Res Ctr, Tajimi, Gifu 5070071, Japan
关键词:
CO ADSORPTION;
OXIDE-SUPPORT;
RH CATALYSTS;
CERIA;
FTIR;
PERFORMANCE;
REDUCTION;
OXIDATION;
MECHANISM;
AL2O3;
D O I:
10.1246/cl.2013.60
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
The catalytic activity of Rh supported on Y-stabilized ZrO2 for NO-CO-C3H6-O-2 reactions under stoichiometric conditions was improved by the addition of 5 mol % CeO2, whereas an excess amount of CeO2 of more than 10 mol % caused a decrease in the NO reduction activity. The improvement was ascribed to the formation of easily reducible Rh species through interaction with a Ce-Zr solid solution.
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页码:60 / 62
页数:3
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