The image furnace for studying thermal reactions involving solids. Application to wood pyrolysis and gasification, and vapours catalytic cracking

被引:14
作者
Authier, Olivier [1 ]
Lede, Jacques [1 ]
机构
[1] Univ Lorraine, CNRS, Lab React & Genie Proc, F-54001 Nancy, France
关键词
Image furnace; Biomass; Pyrolysis; Steam gasification; Catalytic cracking; FLASH PYROLYSIS; STEAM-GASIFICATION; FLUIDIZED-BED; BIOMASS GASIFIERS; OLIVINE CATALYSTS; REMOVAL CATALYST; CELLULOSE; KINETICS; TAR; MODEL;
D O I
10.1016/j.fuel.2013.01.041
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The aim of the present paper is to show that the image furnace is an efficient laboratory device for studying fundamental aspects of high temperature reactions involving a solid. The basic principle relies of solid heating by a concentrated radiation in very clean conditions. The available heat flux densities can be quantitatively controlled inside very large domains, which are quite similar as those encountered in usual pilot plant reactors. The image furnace qualities are experimentally studied in the particular case of biomass thermal conversion. Many results have been already published in the field of pyrolysis reactions. The present paper reports its ability to study also basic reactions of char steam gasification and of catalytic (olivine) cracking of vapours produced by biomass thermal degradation. These three types of reactions (decomposition of a solid; reaction of a gas with a solid; interaction of a vapour with a catalyst) can be studied independently from each other and in the same heat flux densities conditions. The results can be efficiently used for further worthwhile modelling of biomass gasifiers. (c) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:555 / 569
页数:15
相关论文
共 60 条
[1]  
Antal M.J., 1980, P SPEC WORKSH FAST P, P175
[2]  
Auber M, 2009, THESIS INPL LSGC NAN
[3]  
Authier O, 2010, THESIS INPL LRGP NAN
[4]   Wood Fast Pyrolysis: Comparison of Lagrangian and Eulerian Modeling Approaches with Experimental Measurements [J].
Authier, Olivier ;
Ferrer, Monique ;
Mauviel, Guillain ;
Khalfi, Az-Eddine ;
Lede, Jacques .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2009, 48 (10) :4796-4809
[5]  
Barrio M., 2001, Progress in thermochemical biomass conversion, V1, P32, DOI DOI 10.1002/9780470694954.CH2
[6]   Mechanisms of catalyst deactivation [J].
Bartholomew, CH .
APPLIED CATALYSIS A-GENERAL, 2001, 212 (1-2) :17-60
[7]   The continuous self stirred tank reactor:: measurement of the cracking kinetics of biomass pyrolysis vapours [J].
Baumlin, S ;
Broust, F ;
Ferrer, M ;
Meunier, N ;
Marty, E ;
Lédé, J .
CHEMICAL ENGINEERING SCIENCE, 2005, 60 (01) :41-55
[8]   HETEROGENEOUS CRACKING OF WOOD PYROLYSIS TARS OVER FRESH WOOD CHAR SURFACES [J].
BOROSON, ML ;
HOWARD, JB ;
LONGWELL, JP ;
PETERS, WA .
ENERGY & FUELS, 1989, 3 (06) :735-740
[9]   Radiant flash pyrolysis of cellulose - Evidence for the formation of short life time intermediate liquid species [J].
Boutin, O ;
Ferrer, M ;
Lede, J .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1998, 47 (01) :13-31
[10]   Flash pyrolysis of cellulose pellets submitted to a concentrated radiation:: experiments and modelling [J].
Boutin, O ;
Ferrer, M ;
Lédé, J .
CHEMICAL ENGINEERING SCIENCE, 2002, 57 (01) :15-25