Thermochemical properties of di(N,N-di(2,4,6-trinitrophenyl)amino)-ethylenediamine in dimethyl sulfoxide and N-methyl pyrrolidone

被引：5

作者：

Xiao, Li Bai ^{[1
]}

Xing, Xiao Ling ^{[1
]}

Fan, Xue Zhong ^{[1
]}

Zhao, Feng Qi ^{[1
]}

Zhou, Zhi Ming ^{[2
]}

Huang, Hai Feng ^{[2
]}

An, Ting ^{[1
]}

Hao, Hai Xia ^{[1
]}

Pei, Qing ^{[1
]}

机构：

[1] Xian Modern Chem Res Inst, Sci & Technol Combust & Explos Lab, Xian 710065, Peoples R China

[2] Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2012年 / 110卷 / 03期

关键词：

Di(N,N-di(2,4,6-trinitrophenyl)amino)-ethylenediamine; Dimethyl sulfoxide; Kinetics; N-methyl pyrrolidone; Dissolution; DISSOLUTION PROPERTIES; ETHYL-ACETATE; IONIC LIQUIDS;

D O I：

10.1007/s10973-011-2036-1

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The enthalpies of dissolution for di(N,N-di(2,4,6,-trinitrophenyl)amino)-ethylenediamine (DTAED) in dimethyl sulfoxide (DMSO) and N-methyl pyrrolidone (NMP) were measured using a RD496-2000 Calvet microcalorimeter at 298.15 K. Empirical formulae for the calculation of the enthalpies of dissolution (Delta(diss) H) were obtained from the experimental data of the dissolution processes of DTAED in DMSO and NMP. The linear relationships between the rate (k) and the amount of substance (a) were found. The corresponding kinetic equations describing the two dissolution processes were for the dissolution of DTAED in DMSO, and for the dissolution of DTAED in NMP, respectively.

引用

页码：1431 / 1436

页数：6

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