Hollow spheres to nanocups:: Tuning the morphology and magnetic properties of single-crystalline α-Fe2O3 nanostructures

被引：85

作者：

Jagadeesan, Dinesh ^{[1
,2
]}

Mansoori, Uzma ^{[1
,2
]}

Mandal, Pranab ^{[3
]}

Sundaresan, Athinarayanan ^{[3
]}

Eswaramoorthy, Muthusamy ^{[1
,2
]}

机构：

[1] Jawaharlal Nehru Ctr Adv Sci Res, Nanomat & Catalysis Lab, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India

[2] Jawaharlal Nehru Ctr Adv Sci Res, DST Unit Nanosci, Bangalore 560064, Karnataka, India

[3] Jawaharlal Nehru Ctr Adv Sci Res, Magnetism & Superconduct Lab, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 40期

关键词：

crystal engineering; hematite; magnetic properties; nanostructures; template synthesis;

D O I：

10.1002/anie.200802626

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A bottom-up approach has been used to tune the morphology of single-crystalline hematite from hollow spheres to nanocups. The mechanism involves the formation of nanocups through buckling of the spheres, similar to a deflated ball (see picture). As the shape changes, there is a drastic change in magnetic properties. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7685 / 7688

页数：4

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