Degradation of sulfur mustard and 2-chloroethyl ethyl sulfide on Cu-BTC metal organic framework

被引：59
作者：
Roy, Anuradha [1 ]
Srivastava, Avanish Kumar [1 ]
Singh, Beer [1 ]
Mahato, T. H. [1 ]
Shah, Dilip [1 ]
Halve, A. K. [2 ]
机构：
[1] Def Res & Dev Estab, Gwalior 474002, Madhya Pradesh, India
[2] Jiwaji Univ, Sch Studies Chem, Gwalior 474002, Madhya Pradesh, India
来源：
MICROPOROUS AND MESOPOROUS MATERIALS | 2012年 / 162卷
关键词：
Sulfur mustard; Cu-BTC; Degradation kinetics; Hydrolysis; COORDINATION POLYMERS; HETEROGENEOUS CATALYSTS; HYDROGEN STORAGE; FLUORIDE-ION; ADSORPTION; SURFACE; OXIDE; CU-3(BTC)(2); SOLIDS; AGENTS;
D O I：
10.1016/j.micromeso.2012.06.011
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Cu-BTC metal organic framework. HKUST-1 was synthesized by solvothermal method and characterized using surface area analyser, scanning electron microscope, powder X-ray diffractometer, Fourier transform infrared spectrophotometer and thermo gravimetric analyser. HKUST-1 thus produced and characterized, was studied for the degradation of sulfur mustard (HD) and its surrogate 2-chloroethyl ethyl sulfide (CEES) using gas chromatograph coupled with flame ionization detector. From the reaction kinetics it was observed that the CEES degraded faster relative to HD. The rate constant and half life were found to be 0.02 min(-1), 34.65 min and 0.043 min(-1), 16.11 min for HD and CEES respectively. Degradation products were analyzed by gas chromatograph coupled with mass spectrometer. At the same time reusability of the HKUST-1 has also been explored. (c) 2012 Elsevier Inc. All rights reserved.
引用
收藏
页码：207 / 212
页数：6
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