Electro-optical properties of PDLC films using diethylenetriamine (DETA) hardener

被引:4
作者
Ellahi, M. [1 ]
Rafique, M. Y. [2 ]
机构
[1] Univ Karachi, HEJ Res Inst Chem, ICCBS, Karachi 75270, Pakistan
[2] Comsats Inst Informat Technol, Dept Phys, Lahore, Pakistan
关键词
Diethylenetriamine; electro-optical properties (E-O); epoxy resins; polymer dispersed liquid crystal; smart glass; LIQUID-CRYSTAL FILMS; MORPHOLOGY; POLYMERIZATION;
D O I
10.1080/15421406.2016.1222037
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The author's results obtained today and in previous works are summarized. The present work has been performed to investigate the effects of the structure and electro-optical (E-O) properties of epoxy resin based polymer dispersed liquid crystal (PDLC) films smart glass using Diethylenetriamine (DETA) as hardener with 4-cyano-4-penthylbiphenyl (5CB) liquid crystal. In this study we have been prepared PDLC films by the thermal polymerization-induced phase separation (PIPS) method, with a thickness of 10.0 +/- 1.0m controlled by a polyethylene terephathalate (PET) spacer and optimal preparation condition were 25% and 30% 5CB LC, respectively, with a curing time 7hours at 70 degrees c temperature. In addition, PDLC films were prepared with different amounts of DETA to investigate the best ratio of the hardener. Results showed that when the weight ratio of LC 5CB was 30% in PDLC and mol 3% of DETA hardener, then dispersed state of LC were well proportioned, and the variation of transmittance reached the highest value. The optical characterization of the PDLC film indicates an improvement of the angular transmission of visible light. Meanwhile, it is examined that by adjusting the mol% of hardener and LC 5CB content possesses good E-O properties with a low energy efficient method for preparing PDLC smart glass display technology.
引用
收藏
页码:103 / 110
页数:8
相关论文
共 18 条
  • [11] KIM YB, 2009, THIN SOLID FILMS, V517, P3066, DOI DOI 10.1016/J.TSF.2008.11.112
  • [12] POLYMER-DISPERSED LIQUID-CRYSTALS - FROM THE NEMATIC CURVILINEAR ALIGNED PHASE TO FERROELECTRIC-FILMS
    KITZEROW, HS
    [J]. LIQUID CRYSTALS, 1994, 16 (01) : 1 - 31
  • [13] Electro-optic characteristics and switching principle of a nematic liquid crystal cell controlled by fringe-field switching
    Lee, SH
    Lee, SL
    Kim, HY
    [J]. APPLIED PHYSICS LETTERS, 1998, 73 (20) : 2881 - 2883
  • [14] STABILIZATION OF EPOXY-BASED POLYMER-DISPERSED LIQUID-CRYSTAL FILMS BY ADDITION OF EXCESS HARDENER
    MURAI, H
    GOTOH, T
    [J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1993, 226 : 13 - 23
  • [15] Polymer dispersed liquid crystal film for variable-transparency glazing
    Park, Sucheol
    Hong, Jin Who
    [J]. THIN SOLID FILMS, 2009, 517 (10) : 3183 - 3186
  • [16] The UV polymerisation temperature dependence of polymer-dispersed liquid crystals based on epoxies/acrylates hybrid polymer matrix components
    Song, Ping
    Cao, Hui
    Wang, Feifei
    Liu, Fang
    Wang, Jingjing
    Ellahi, Mujtaba
    Li, Fasheng
    Yang, Huai
    [J]. LIQUID CRYSTALS, 2012, 39 (09) : 1131 - 1140
  • [17] Studies on electro-optical properties of polymer dispersed liquid crystal films based on epoxy resins prepared by UV-initiated cationic polymerisation
    Song, Ping
    Yu, Lilong
    Cao, Hui
    Wang, Feifei
    Liu, Fang
    Zhang, Cuihong
    Yang, Chaoyong
    Yang, Huai
    [J]. LIQUID CRYSTALS, 2012, 39 (03) : 313 - 321
  • [18] Achieving high light efficiency and fast response time in fringe field switching mode using a liquid crystal with negative dielectric anisotropy
    Yun, Hong Jun
    Jo, Mi Hyeon
    Jang, In Won
    Lee, Seung Hee
    Ahn, Seon Hong
    Hur, Hae Jin
    [J]. LIQUID CRYSTALS, 2012, 39 (09) : 1141 - 1148