Dynamic surface properties of foaming agent C12E8

被引:4
|
作者
Han, GB [1 ]
Wu, JT
Vignes-Adler, M
机构
[1] Xiamen Univ, Inst Phys Chem, State Key Lab Phys Chem Solid Surface, Xiamen 361005, Peoples R China
[2] CNRS, F-75700 Paris, France
关键词
surface adsorption model; Frumkin state equation; diffusion coefficient; relaxation characteristic frequency; limiting dilational modulus;
D O I
10.3866/PKU.WHXB19990408
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The dynamic surface dilational properties of C12E8 aqueous solution were investigated by the damped longitudinal wave method, The comparison between the experimental resultant and the three adsorption models (diffusion controlled, adsorption-desorption controlled and mixted model) shows that bellow the cmc the adsorption and desorption rate is rapid and the rate of adsorption is controlled by the diffusional exchange between bulk and subsurface with the diffusion coefficient which is dependent on the concentration at lower concentration and independent of concentration at higher concentration, The effects of he increase of the limiting dilational modulus at high frequency and the characteristic frequency of relaxation when the concentration of C12E8 increase has been related to the restoration mechanism of surface tension gradient due to the stretched surface.
引用
收藏
页码:327 / 332
页数:6
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