Enhanced cyclic performance of SnO2-CuO-graphite nano-sheets as anode for Li-ion battery

被引:25
|
作者
Lu, Bin [1 ]
Wang, Hui [1 ]
Hu, Renzong [1 ]
Yang, Lichun [1 ]
Liu, Jun [1 ]
Liu, Jiangwen [1 ]
Zhu, Min [1 ]
机构
[1] South China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Guangdong, Peoples R China
基金
美国国家科学基金会;
关键词
Tin oxide; Copper oxide; Composite materials; Energy storage and conversion; ELECTROCHEMICAL PERFORMANCE; LITHIUM STORAGE; SNO2; NANOWIRE; HIGH-CAPACITY; LITHIATION; OXIDE;
D O I
10.1016/j.matlet.2016.08.093
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A ternary nanocomposite of SnO2, CuO and graphite is prepared by bead milling in alcohol, during which the graphite is greatly thinned to form graphite nano-sheets that wrapping the SnO2 and in-situ formed CuO nanoparticles. This unique microstructure of SnO2-CuO-graphite nanocomposite benefits the reversible formation of SnO2 and CuO in the repeatedly charging process, and thus significantly improves the cyclic stability and rate capability. The reversible capacity of this ternary nanocomposite remains 561.2 mAh g(-1) at 0.1 A g(-1) after 150 cycles, much higher than that of the SnO2-graphite, and CuO-graphite hybrids. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:9 / 12
页数:4
相关论文
共 50 条
  • [41] Assembled-sheets-like MoO3 anodes with excellent electrochemical performance in Li-ion battery
    Huang, Jianfeng
    Yan, Jingwen
    Li, Jiayin
    Cao, Liyun
    Xu, Zhanwei
    Wu, Jianpeng
    Zhou, Lei
    Luo, Yijia
    JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 688 : 588 - 595
  • [42] Regulated Breathing Effect of Silicon Negative Electrode for Dramatically Enhanced Performance of Li-Ion Battery
    Xiao, Xingcheng
    Zhou, Weidong
    Kim, Youngnam
    Ryu, Ill
    Gu, Meng
    Wang, Chongmin
    Liu, Gao
    Liu, Zhongyi
    Gao, Huajian
    ADVANCED FUNCTIONAL MATERIALS, 2015, 25 (09) : 1426 - 1433
  • [43] Scalable synthesis of nano-Si embedded in porous C and its enhanced performance as anode of Li-ion batteries
    Zhuang, Xiangyang
    Zhang, Yao
    He, Lingxiao
    Zhu, Yunfeng
    Tian, Qifeng
    Guo, Xinli
    Chen, Jian
    Li, Liquan
    Wang, Quan
    Song, Guanzhou
    Yan, Xiaoxiao
    ELECTROCHIMICA ACTA, 2017, 249 : 166 - 172
  • [44] Nano-graphite platelet loaded with LiFePO4 nanoparticles used as the cathode in a high performance Li-ion battery
    Kim, Haegyeom
    Kim, Hyungsub
    Kim, Sung-Wook
    Park, Kyu-Young
    Kim, Jinsoo
    Jeon, Seokwoo
    Kang, Kisuk
    CARBON, 2012, 50 (05) : 1966 - 1971
  • [45] Scalable synthesis of Li2GeO3/expanded graphite as a high-performance anode for Li-ion batteries
    Li, Fangkun
    Wang, Xinyi
    He, Weixin
    Xu, Xijun
    Liu, Zhengbo
    Shen, Jiadong
    Hu, Yunfei
    Chen, Zhonghua
    Liu, Jun
    JOURNAL OF ALLOYS AND COMPOUNDS, 2022, 898
  • [46] Atomic layer deposition of SnO2 on MXene for Li-ion battery anodes
    Ahmed, Bilal
    Anjum, Dalaver H.
    Gogotsi, Yury
    Alshareef, Husam N.
    NANO ENERGY, 2017, 34 : 249 - 256
  • [47] The mechanistic exploration of porous activated graphene sheets-anchored SnO2 nanocrystals for application in high-performance Li-ion battery anodes
    Yang, Yingchang
    Ji, Xiaobo
    Lu, Fang
    Chen, Qiyuan
    Banks, Craig E.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (36) : 15098 - 15105
  • [48] Large-Scale Synthesis of SnO2 Nanotube Arrays as High-Performance Anode Materials of Li-Ion Batteries
    Wang, Jiazheng
    Du, Ning
    Zhang, Hui
    Yu, Jingxue
    Yang, Deren
    JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (22) : 11302 - 11305
  • [49] In Situ Mechanistic Elucidation of Superior Si-C-Graphite Li-Ion Battery Anode Formation with Thermal Safety Aspects
    Parekh, Mihit H.
    Sediako, Anton D.
    Naseri, Ali
    Thomson, Murray J.
    Pol, Vilas G.
    ADVANCED ENERGY MATERIALS, 2020, 10 (02)
  • [50] Design of advanced thick anode for Li-ion battery by inserting a graphite/polymer buffer layer: An in-situ mechanical study
    Zeng, Wenduo
    Xing, Junheng
    Chen, Jimmy Ching-Ming
    Ng, K. Y. Simon
    Oshihara, Kenzo
    Cheng, Mark Ming-Cheng
    ELECTROCHIMICA ACTA, 2018, 281 : 282 - 291