Synthesis and evaluation of photophysical properties of Series of π-conjugated oxazole dyes

被引:41
作者
Mahuteau-Betzer, Florence [1 ]
Piguel, Sandrine [1 ,2 ]
机构
[1] Ctr Univ, CNRS, UMR 176, Inst Curie, F-91405 Orsay, France
[2] Univ Paris 11, F-91405 Orsay, France
关键词
Oxazole; Direct C-H bond functionalization; Fluorescence; Dyes; CATALYZED DIRECT ARYLATION; 2-PHOTON ABSORPTION; DIRECT ALKYNYLATION; ALKENYLATION; FLUORESCENCE; AZOLES; COPPER; SCINTILLATION; PROBES;
D O I
10.1016/j.tetlet.2013.04.037
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Incorporation of pi-conjugated spacers at the 2 or 5 position of a 2,5-disubstitutedaryloxazole led to new series of fluorescent dyes. They show emissions from visible to 700 nm along with significant Stokes shift up to 208 nm and a strong solvatochromic fluorescence. These compounds are easily accessible in one step through direct C-H bond functionalization. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3188 / 3193
页数:6
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