A study on the effect of new prepared amide cationic amphipathic on the corrosion inhibition of API N80 steel pipelines in oil wells industries

被引:14
作者
Shaban, Samy [1 ]
Fouda, Abd Elaziz [2 ]
Elmorsi, Mohamed [3 ]
Fayed, Tarek [3 ]
Azazy, Omar [4 ]
机构
[1] Egyptian Petr Res Inst, Petrochem Dept, Cairo, Egypt
[2] El Mansoura Univ, Dept Chem, Almansora, Egypt
[3] Tanta Univ, Dept Chem, Tanta, Egypt
[4] GPC, Corros Control Sect, Red Sea Qharb, Egypt
关键词
Potentiodynamic polarization; Langmuir isotherm; AFM; Impedance spectroscopy; Cationic surfactant; Theoretical study; CARBON-STEEL; MILD-STEEL; ACIDIC MEDIUM; HCL SOLUTION; FORMATION WATER; SURFACTANTS; ADSORPTION; BEHAVIOR; DERIVATIVES; TRIAZOLE;
D O I
10.1108/ACMM-08-2017-1824
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Purpose The purpose of this study is to inspect the corrosion inhibition of API N80 steel pipelines in uninhibited solution and inhibited with a synthesized surfactant compound [N-(3-(dimethyl octyl ammonio) propyl) palmitamide bromide] (DMDPP), which is prepared through a simple and applicable method. Design/methodology/approach Weight loss was inspected at five different temperatures of 25 degrees C, 30 degrees C, 40 degrees C, 50 degrees C and 60 degrees C Potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation were used at room temperature. Density functional theory was used to study the relation between the molecular structure and inhibition theoretically. Findings Adsorption of the prepared DMDPP fits the Langmuir isotherm model. The inhibition efficiency of the prepared DMDPP amphipathic inhibitor is directly proportional to temperature increase. Polarization results reveal that the investigated DMDPP amphipathic compound behaves as a mixed-type inhibitor. EIS spectra produced one individual capacitive loop. Originality/value The originality is the preparation of cationic surfactants through a simple method, which can be used as corrosion inhibitors in oil production. The synthesized inhibitors were prepared from low-price materials. The work studied the behavior of the synthesized surfactants in inhibiting the corrosion of the steel in an acidic medium. Electrochemical and theoretical studies were presented, besides gravimetric and surface examination.
引用
收藏
页码:197 / 209
页数:13
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