Relations between coarsening and densification and mass transport path in solid-state sintering of ceramics: Model analysis

被引:37
作者
Shi, JL [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
关键词
D O I
10.1557/JMR.1999.0188
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The correlations between coarsening (including grain and pore growth) and densification, and the effects of mass transport on particle coarsening and densification were discussed based on the simple particle array models and for the real particle compacts. Grain boundary motion could cause particle coarsening only under a certain particle size distribution but not densification; mass transport is reasoned to contribute to both grain growth (particle coarsening) and shrinkage for one-dimensional particle arrays. Under a certain limitation for the change of the particle size aspect ratio during sintering, very limited effects of grain grown by itself on the shrinkage of particle arrays through reinitiating the sintering could be found. For a real powder compact system, mass transport between the particles, which surround a pore, contributes to the particle coarsening and densification when the pore is thermodynamically unstable and only to particle coarsening when the pore is thermodynamically stable. The mass transport mechanism for both particle coarsening and densification would be the same, which cannot exclude, at least on thermodynamics, the contribution from surface diffusion in the intermediate stage of sintering.
引用
收藏
页码:1378 / 1388
页数:11
相关论文
共 24 条
  • [1] Brook R.J., 1976, Treatise on Materials Science & Technology, V9, P331
  • [3] COBLE RL, 1961, J APPL PHYS, V32, P587
  • [4] Coblenz W., 1980, MAT SCI RES, V13, P141
  • [5] Exner H. E., 1983, Physical metallurgy. Third revised and enlarged edition, P1885
  • [6] EXNER HE, 1987, SINTERING KEY PAPERS, P157
  • [7] FRANCOIS B, 1967, SINTERING RELATED PH, P499
  • [8] GUPTA TK, 1972, J AM CERA SOC, V55, P176
  • [9] HARMER MP, 1981, J BR CERAM SOC, V80, P147
  • [10] HARMER MP, 1985, ADV CERAM, V10, P679