Bulk-Processed Pd Nanocube-Poly(methyl methacrylate) Nanocomposites as Plasmonic Plastics for Hydrogen Sensing

被引：27

作者：

Darmadi, Iwan ^{[1
]}

Stolas, Alicja ^{[2
]}

Ostergren, Ida ^{[2
]}

Berke, Barbara ^{[1
]}

Nugroho, Ferry Anggoro Ardy ^{[1
]}

Minelli, Matteo ^{[3
]}

Lerch, Sarah ^{[2
]}

Tanyeli, Irem ^{[1
,4
]}

Lund, Anja ^{[2
]}

Andersson, Olof ^{[4
]}

Zhdanov, Vladimir P. ^{[5
]}

Liebi, Marianne ^{[1
]}

Moth-Poulsen, Kasper ^{[2
]}

Mueller, Christian ^{[2
]}

Langhammer, Christoph ^{[1
]}

机构：

[1] Chalmers Univ Technol, Dept Phys, S-41296 Gothenburg, Sweden

[2] Chalmers Univ Technol, Dept Chem & Chem Engn, S-41296 Gothenburg, Sweden

[3] Univ Bologna, Dept Civil Chem Environm & Mat Engn, I-40131 Bologna, Italy

[4] Insplorion AB, S-41390 Gothenburg, Sweden

[5] Russian Acad Sci, Boreskov Inst Catalysis, Novosibirsk 630090, Russia

来源：

ACS APPLIED NANO MATERIALS | 2020年 / 3卷 / 08期

关键词：

plasmonic nanocomposites; nanoparticles; polymer matrix; melt processing; 3D printing; plasmonic hydrogen sensing; PALLADIUM; NANOFABRICATION; SELECTIVITY; HYSTERESIS;

D O I：

10.1021/acsanm.0c01907

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Nanoplasmonic hydrogen sensors are predicted to play a key role in safety systems of the emerging hydrogen economy. Pd nanoparticles are the active material of choice for sensor prototype development due to their ability to form a hydride at ambient conditions, which creates the optical contrast. Here, we introduce plasmonic hydrogen sensors made from a thermoplastic nanocomposite material, that is, a bulk material that can be molded with standard plastic processing techniques, such as extrusion and three-dimensional (3D) printing, while at the same time being functionalized at the nanoscale. Specifically, our plasmonic plastic is composed of hydrogensensitive and plasmonically active Pd nanocubes mixed with a poly(methyl methacrylate) matrix, and we optimize it by characterization from the atomic to the macroscopic level. We demonstrate meltprocessed deactivation-resistant plasmonic hydrogen sensors, which retain full functionality even after SO weeks. From a wider perspective, we advertise plasmonic plastic nanocomposite materials for application in a multitude of active plasmonic technologies since they provide efficient scalable processing and almost endless functional material design opportunities via tailored polymer- colloidal nanocrystal combinations.

引用

页码：8438 / 8445

页数：8

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