A macrocyclic aromatic pyridone pentamer as a highly efficient organocatalyst for the direct arylations of unactivated arenes

被引:107
|
作者
Zhao, Huaiqing [1 ]
Shen, Jie [1 ]
Guo, Juanjuan [1 ]
Ye, Ruijuan [1 ]
Zeng, Huaqiang [1 ]
机构
[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
关键词
TERT-BUTOXIDE; ARYL HALIDES; RECOGNITION; FOLDAMERS; BENZENE;
D O I
10.1039/c3cc00019b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A macrocyclic aromatic pyridone pentamer was shown to catalyze highly efficient transition-metal-free arylations of unactivated aromatic C-H bonds with aryl iodides and bromides in the presence of potassium tert-butoxide.
引用
收藏
页码:2323 / 2325
页数:3
相关论文
共 30 条
  • [1] A Foldamer-Based Organocatalyst for Direct Arylations of Unactivated Arenes
    Zhao, Huaiqing
    Shen, Jie
    Ren, Changliang
    Zeng, Wei
    Zeng, Huaqiang
    ORGANIC LETTERS, 2017, 19 (08) : 2190 - 2193
  • [2] Urea-based organocatalyst catalyzed direct C-H bond arylations of unactivated arenes
    Zhao, Huaiqing
    Xu, Xiangwen
    Wu, Wei
    Zhang, Wei
    Zhang, Yunxian
    CATALYSIS COMMUNICATIONS, 2018, 111 : 95 - 99
  • [3] Proline Catalyzes Direct C-H Arylations of Unactivated Arenes
    Tanimoro, Kouichi
    Ueno, Minoru
    Takeda, Kazutaka
    Kirihata, Mitsunori
    Tanimori, Shinji
    JOURNAL OF ORGANIC CHEMISTRY, 2012, 77 (18): : 7844 - 7849
  • [4] Size-dependent patterned recognition and extraction of metal ions by a macrocyclic aromatic pyridone pentamer
    Shen, Jie
    Ma, Wenliang
    Yu, Lin
    Li, Jin-Bo
    Tao, Hu-Chun
    Zhang, Kun
    Zeng, Huaqiang
    CHEMICAL COMMUNICATIONS, 2014, 50 (84) : 12730 - 12733
  • [5] Direct C-H Arylations of Unactivated Arenes Catalyzed by Amido-Functionalized Imidazolium Salts
    Ghosh, Debalina
    Lee, Jhen-Yi
    Liu, Chian-Yu
    Chiang, Yen-Hsin
    Lee, Hon Man
    ADVANCED SYNTHESIS & CATALYSIS, 2014, 356 (2-3) : 406 - 410
  • [6] An efficient bimetallic rhodium catalyst for the direct arylation of unactivated arenes
    Proch, Sebastian
    Kempe, Rhett
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (17) : 3135 - 3138
  • [7] p-Toluenesulfonohydrazide as Highly Efficient Initiator for Direct C-H Arylation of Unactivated Arenes
    Song, Qiao
    Zhang, Dongmei
    Zhu, Qihua
    Xu, Yungen
    ORGANIC LETTERS, 2014, 16 (20) : 5272 - 5274
  • [8] A highly efficient organocatalyst for direct Aldol reactions of ketones with aldedydes
    Tang, Z
    Yang, ZH
    Chen, XH
    Cun, LF
    Mi, AQ
    Jiang, YZ
    Gong, LZ
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (25) : 9285 - 9289
  • [9] Highly efficient ring closure of aromatic dialdehydes to macrocyclic allenes
    Brody, MS
    Williams, RM
    Finn, MG
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (15) : 3429 - 3433
  • [10] Highly efficient gold(III)-catalyzed intermolecular hydroarylation of unactivated alkenes with arenes under mild conditions
    Xiao, Ya-Ping
    Liu, Xin-Yuan
    Che, Chi-Ming
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (04) : 494 - 501