Simple is best: Diamine zinc complexes as unexpected catalysts in lactide polymerisation

被引：24

作者：

Eckert, Prisca K. ^{[1
]}

Vieira, Ines dos Santos ^{[1
]}

Gessner, Viktoria H. ^{[2
]}

Boerner, Janna ^{[3
]}

Strohmann, Carsten ^{[1
]}

Herres-Pawlis, Sonja ^{[1
]}

机构：

[1] Tech Univ Dortmund, Fak Chem, D-44227 Dortmund, Germany

[2] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

[3] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

POLYHEDRON | 2013年 / 49卷 / 01期

关键词：

Biodegradable Polymers; Amines; Zinc; Ring-opening polymerisation; Coordination compounds; RING-OPENING POLYMERIZATION; SINGLE-SITE CATALYSTS; COORDINATION CHEMISTRY; BIODEGRADABLE POLYMERS; MAGNESIUM; INITIATORS; ALKOXIDE; TRANS-1,2-DIAMINOCYCLOHEXANE;

D O I：

10.1016/j.poly.2012.09.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of monomeric coordination compounds containing zinc(II) chloride or zinc(II) bromide and the 1,2-diamine ligands TMEDA, TEEDA, (R,R)-TMCDA, (R,R)-TECDA and cis-TMCDA have been synthesised and structurally characterised using X-ray diffraction analysis. All but one complex could be successfully used as initiators for the solvent-free ring-opening polymerisation of D,L-lactide. In particular, the polylactide (PLA) prepared with compounds containing (R,R)-TECDA is obtainable in high yields with molecular weights suitable for industrial applications. Thus a class of stable, easy to synthesise and efficient PLA catalysts with neutral ligands is introduced. (c) 2012 Elsevier Ltd. All rights reserved.

引用

页码：151 / 157

页数：7

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