Microporous lanthanide metal-organic frameworks

被引:99
作者
Chen, Yao [1 ]
Ma, Shengqian [1 ]
机构
[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA
关键词
catalysis; gas adsorption; lanthanide MOF; luminescence; microporous; sensor; POROUS COORDINATION POLYMERS; SECONDARY BUILDING UNITS; HIGH THERMAL-STABILITY; MAGNETIC-PROPERTIES; GAS-ADSORPTION; LUMINESCENCE PROPERTIES; SOLVOTHERMAL SYNTHESIS; CATENATION ISOMERISM; SORPTION PROPERTIES; HYBRID MATERIALS;
D O I
10.1515/revic-2012-0003
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Microporous metal-organic frameworks (MOFs) based on lanthanide metal ions or clusters represent a group of porous materials, featuring interesting coordination, electronic, and optical properties. These attractive properties in combination with the porosity make microporous lanthanide MOFs (Ln-MOFs) hold the promise for various applications. This review is to provide an overview of the current status of the research in microporous Ln-MOFs, and highlight their potential as types of multifunctional materials for applications in gas/solvent adsorption and separation, luminescence and chemical sensing and catalysis.
引用
收藏
页码:81 / 100
页数:20
相关论文
共 108 条
[1]   Lanthanide-Based Luminescent Hybrid Materials [J].
Binnemans, Koen .
CHEMICAL REVIEWS, 2009, 109 (09) :4283-4374
[2]   3-D Lanthanide Metal-Organic Frameworks: Structure, Photoluminescence, and Magnetism [J].
Black, Cory A. ;
Costa, Jose Sanchez ;
Fu, Wen Tian ;
Massera, Chiara ;
Roubeau, Olivier ;
Teat, Simon J. ;
Aromi, Guillem ;
Gamez, Patrick ;
Reedijk, Jan .
INORGANIC CHEMISTRY, 2009, 48 (03) :1062-1068
[3]   Lanthanide Luminescence for Biomedical Analyses and Imaging [J].
Buenzli, Jean-Claude G. .
CHEMICAL REVIEWS, 2010, 110 (05) :2729-2755
[4]   Tuning the porosity of lanthanide MOFs with 2,5-pyrazinedicarboxylate and the first in situ hydrothermal carboxyl transfer [J].
Cai, Bin ;
Yang, Ping ;
Dai, Jing-Wei ;
Wu, Jian-Zhong .
CRYSTENGCOMM, 2011, 13 (03) :985-991
[5]   Series of lanthanide-alkali metal-organic frameworks exhibiting luminescence and permanent microporosity [J].
Chandler, Brett D. ;
Yu, Joanne O. ;
Cramb, David T. ;
Shimizu, George K. H. .
CHEMISTRY OF MATERIALS, 2007, 19 (18) :4467-4473
[6]   A luminescent microporous metal-organic framework for the recognition and sensing of anions [J].
Chen, Banglin ;
Wang, Liangbo ;
Zapata, Fatima ;
Qian, Guodong ;
Lobkovsky, Emil B. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (21) :6718-+
[7]   Luminescent open metal sites within a metal-organic framework for sensing small molecules [J].
Chen, Banglin ;
Yang, Yu ;
Zapata, Fatima ;
Lin, Guannan ;
Qian, Guodong ;
Lobkovsky, Emil B. .
ADVANCED MATERIALS, 2007, 19 (13) :1693-+
[8]   A Luminescent Metal-Organic Framework with Lewis Basic Pyridyl Sites for the Sensing of Metal Ions [J].
Chen, Banglin ;
Wang, Liangbo ;
Xiao, Yunqing ;
Fronczek, Frank R. ;
Xue, Ming ;
Cui, Yuanjing ;
Qian, Guodong .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (03) :500-503
[9]   Nanosized lanthanide oxide rods in I1O3 hybrid organic-inorganic frameworks involving in situ ligand synthesis [J].
Chen, Lan-Fen ;
Zhang, Jian ;
Ren, Guo-Qiang ;
Li, Zhao-Ji ;
Qin, Ye-Yan ;
Yin, Pei-Xiu ;
Cheng, Jian-Kai ;
Yao, Yuan-Gen .
CRYSTENGCOMM, 2008, 10 (08) :1088-1092
[10]   Microporous metal-organic frameworks built on a Ln3 cluster as a six-connecting node [J].
Chen, XY ;
Zhao, B ;
Shi, W ;
Xia, J ;
Cheng, P ;
Liao, DZ ;
Yan, SP ;
Jiang, ZH .
CHEMISTRY OF MATERIALS, 2005, 17 (11) :2866-2874