Flotation of oxidized minerals of copper using a new synthetic chelating reagent as collector

被引:79
作者
Barbaro, M
Urbina, RH
Cozza, C
Fuerstenau, D
Marabini, A
机构
[1] UNIV SONORA,DEPT INGN QUIM & MET,SONORA,MEXICO
[2] UNIV CALIF BERKELEY,BERKELEY,CA 94720
关键词
flotation; chrysocolla minerals; chelating reagents;
D O I
10.1016/S0301-7516(97)00045-8
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A new synthetic reagent containing a mixed aliphatic-aromatic structure, with a hydrocarbon chain and an aminothiophenol chelating group, has proven to be an effective collector for the flotation of chrysocolla minerals. The flotation is optimum in the narrow pH range of 5.5 to 6, falls sharply at pH 5, and is moderate in the pH range 7 to 11, Infrared spectra indicate that copper aminothiophenolate chelates are formed on the surface of the chrysocolla under the conditions of maximum flotation. (C) 1997 Elsevier Science B.V.
引用
收藏
页码:275 / 287
页数:13
相关论文
共 31 条
  • [21] NAGARAY DR, 1979, T SME AIME, V26, P1892
  • [22] NAGARAY DR, 1981, MIN ENG, V38, P1351
  • [23] Nakanishi K., 1962, IR ABSORPTION SPECTR
  • [24] OMAR JH, 1986, SURF CLOATING TECHNO, V29, P141
  • [25] PETERSON MD, 1965, T AIME, V233, P388
  • [26] PRADIP, 1987, T INDIAN I METALS, V40, P287
  • [27] TRANSITION-METAL COMPLEXES OF DEPROTONATED 2-MERCAPTOBENZOXAZOLE - STUDY OF THIOL-THIOKETO FORM EQUILIBRIUM
    PRETI, C
    TOSI, G
    [J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1977, 55 (08): : 1409 - 1414
  • [28] INFRARED STUDIES OF ADSORBED SPECIES ON RUTILE AT THE SOLID VAPOR AND SOLID LIQUID INTERFACES
    ROCHESTER, CH
    [J]. COLLOIDS AND SURFACES, 1986, 21 : 205 - 217
  • [29] Ross S.D., 1974, The Infrared Spectra of Minerals, VVolume 4
  • [30] SHRIVER DF, 1994, CHIMICA INORGANICA