Studies on copolymerization of poly(ethylene oxide) macromer and methyl methacrylate with their copolymers

被引:0
|
作者
Guo, SR [1 ]
Feng, LX [1 ]
Yu, XJ [1 ]
Yang, SL [1 ]
机构
[1] ZHEJIANG UNIV,DEPT POLYMER,HANGZHOU 310027,PEOPLES R CHINA
来源
关键词
PEO macromer; copolymerization; antithrombogenic property; microphase separated structure;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Copolymerization of alpha-methacryloyl-omega-phenyl poly (ethylene oxide)(PEO) macromers with methyl methacrylate(MMA) in toluene using AIBN as initiator was studied, The effects of amount of initiator, total monomer concentration, reaction time and charging ratio of the macromer to MMA on the composition and molecular weight of the graft copolymer were studied, The purified copolymer was characterized with IR, H-1 NMR, DSC and GPC. Microphase separated structure of the copolymer was observed with TEM and the antithrombogenic properties were evaluated.
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页码:156 / 159
页数:4
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