High CO2 Uptake Capacity and Selectivity in a Fascinating Nanotube-Based Metal Organic Framework

被引：52

作者：

Wu, Yun-Long ^{[1
]}

Qian, Jinjie ^{[2
]}

Yang, Guo-Ping ^{[1
]}

Yang, Fan ^{[1
]}

Liang, Yu-Tong ^{[1
]}

Zhang, Wen-Yan ^{[1
]}

Wang, Yao-Yu ^{[1
]}

机构：

[1] Northwest Univ, Shaanxi Key Lab Physicoinorgan Chem, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ,Coll Chem & Mat Sci, Xian 710127, Peoples R China

[2] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China

来源：

INORGANIC CHEMISTRY | 2017年 / 56卷 / 02期

基金：

中国博士后科学基金;

关键词：

CARBON-DIOXIDE CAPTURE; SORPTION BEHAVIOR; ADSORPTION; SITES; CHEMISTRY; CO2/N-2; CO2/CH4; STORAGE; O-2; CH4;

D O I：

10.1021/acs.inorgchem.6b02491

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An unusual porous metal organic framework has been synthesized by using Pb(II) and rigid V-shaped 4,4'-(pyridine-3,5-diyOdiisophthalic acid (H4L). Structure analysis reveals that there exist 1D cylindrical 14.26 A and triangular prism 10.69 X 10.69 X 10.69 angstrom(3) nanotubes in the framework. Gas sorption behavior of the nanoporous MOF shows a relatively high capacity and selectivity of CO2 over CH4.

引用

页码：908 / 913

页数：6

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