A rechargeable aluminum-ion battery utilizing a copper hexacyanoferrate cathode in an organic electrolyte

被引：136
|
作者：
Reed, L. D. [1 ]
Ortiz, S. N. [1 ]
Xiong, M. [1 ]
Menke, E. J. [1 ]
机构：
[1] Univ Calif, Merced, CA 95343 USA
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 76期
关键词：
PRUSSIAN BLUE ANALOG; INTERCALATION; STABILITY; FRAMEWORK; INSERTION; ENERGY;
D O I：
10.1039/c5cc06053b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reversible aluminum intercalation/deintercalation from an organic electrolyte into copper hexacyanoferrate is presented. Evidence suggest that an aluminum-solute complex is the intercalating species. The system shows initial discharge capacities as high as 60 mA h g(-1) and reversible capacities between 5 and 14 mA h g(-1), with capacity typically fading after 10 to 15 cycles.
引用
收藏
页码：14397 / 14400
页数：4
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