EPR characterization of Co-doped ZnO microwires and distant spin-pair coupling

被引:14
作者
Savoyant, A. [1 ]
Giovannelli, F. [2 ]
Delorme, F. [2 ]
Stepanov, A. [1 ]
机构
[1] Aix Marseille Univ, FST, CNRS UMR 6242, IM2NP, F-13397 Marseille 20, France
[2] Univ Francois Rabelais Tours, CNRS, CEA, INSA CVL,GREMAN UMR 7347,IUT Blois, F-41029 Blois, France
关键词
electron paramagnetic resonance; zinc oxyde; microwires; SEMICONDUCTORS;
D O I
10.1088/0268-1242/30/7/075004
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Cobalt-doped ZnO microwires have been grown by the optical furnace method with Co concentration in the range 0-5%. The high crystallinity of these objects is demonstrated by the use of electron paramagnetic resonance (EPR), in which Co2+ ions serve as magnetic probes. The spin state of these isolated magnetic impurities and their location in the host crystal are addressed by EPR, as well as the coupling constant between non-nearest Co2+-Co2+ neighbors. Eight of these distant spin pairs are detected, among which two are confirmed to be ferromagnetic. The problem of their localization in the wurtzite structure is discussed.
引用
收藏
页数:7
相关论文
共 25 条
[1]   EPR spectroscopy of weak exchange interactions between Co2+ ions in ZnO [J].
Azamat, D. V. ;
Dejneka, A. ;
Trepakov, V. A. ;
Jastrabik, L. ;
Fanciulli, M. ;
Ivanov, V. Y. ;
Godlewski, M. ;
Sokolov, V. I. ;
Rosa, J. ;
Badalyan, A. G. .
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2011, 5 (04) :138-140
[2]  
Behringer B E, 1958, J CHEM PHYS, V29, P537
[3]   Fast piezoresistive sensor and UV photodetector based on Mn-doped ZnO nanorods [J].
Chey, Chan Oeurn ;
Liu, Xianjie ;
Alnoor, Hatim ;
Nur, Omer ;
Willander, Magnus .
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2015, 9 (01) :87-91
[4]   Competing exchange interactions in Co-doped ZnO: Departure from the superexchange picture [J].
D'Ambrosio, S. ;
Pashchenko, V. ;
Mignot, J. -M. ;
Ignatchik, O. ;
Kuzian, R. O. ;
Savoyant, A. ;
Golacki, Z. ;
Grasza, K. ;
Stepanov, A. .
PHYSICAL REVIEW B, 2012, 86 (03)
[5]   Hole states in wide band-gap diluted magnetic semiconductors and oxides [J].
Dietl, Tomasz .
PHYSICAL REVIEW B, 2008, 77 (08)
[6]   ZnO nanostructures for optoelectronics: Material properties and device applications [J].
Djurisic, A. B. ;
Ng, A. M. C. ;
Chen, X. Y. .
PROGRESS IN QUANTUM ELECTRONICS, 2010, 34 (04) :191-259
[7]  
Estle T. L., 1961, B AM PHYS SOC, V6, P445
[8]   Magnetism in ZnO nanowire with Fe/Co codoping: First-principles density functional calculations [J].
Ghosh, S. ;
Wang, Q. ;
Das, G. P. ;
Jena, P. .
PHYSICAL REVIEW B, 2010, 81 (23)
[9]   Synthesis of Al doped ZnO nanoparticles by aqueous coprecipitation [J].
Giovannelli, F. ;
Ndimba, A. Ngo ;
Diaz-Chao, P. ;
Motelica-Heino, M. ;
Raynal, P. I. ;
Autret, C. ;
Delorme, F. .
POWDER TECHNOLOGY, 2014, 262 :203-208
[10]   Synthesis of ZnO microwires and tetrapods by optical furnace [J].
Giovannelli, F. ;
Rajonson, G. ;
Wolfman, J. ;
Delorme, F. .
MATERIALS LETTERS, 2013, 107 :194-196