Mesoporous thin films: Properties and applications

被引:28
作者
Innocenzi, Plinio [1 ,2 ]
Costacurta, SteFano [1 ,2 ]
Kidchob, Tongjt [1 ,2 ]
Malfatti, Luca [1 ,2 ]
Falcaro, Paolo [3 ]
Soler-Illia, Galo [4 ,5 ]
机构
[1] Univ Sassari, Nanoworld Inst, Lab Sci Mat & Nanotechnol, Palazzo Del Pou Salit,Piazza Duolno 6, I-07041 Alghero, Italy
[2] CR INSTM, I-07041 Alghero, Italy
[3] Associazione CIVEN Nano Fabricat Facil, I-30175 Venice, Italy
[4] CNEA, Gerencia Quim, RA-B1650KNA Buenos Aires, DF, Argentina
[5] Consejo Nacl Invest Cient & Tecn, RA-C1033AAV Buenos Aires, DF, Argentina
来源
SOL-GEL METHODS FOR MATERIALS PROCESSING: FOCUSING ON MATERIALS FOR POLLUTION CONTROL, WATER PURIFICATION, AND SOIL REMEDIATION | 2008年
关键词
mesoporous; thin-films; self-assembly; sol-gel;
D O I
10.1007/978-1-4020-8514-7_7
中图分类号
Q14 [生态学(生物生态学)];
学科分类号
071012 ; 0713 ;
摘要
Mesoporous films are a fine example of a self-assembled nanosystem, containing ordered porosity in the 2-50 run range. A great number of characteristics, including framework nature (composition, crystallinity), high Surface area, port! dimension, shape, surface, accessibility and pore array symmetry and interconnection can be tuned using green chemistry synthetic techniques. These materials present potentials in several fields where a large functional interfacial area contained in a robust framework is required. The capability of changing in a separate way the characteristics of the inorganic framework and the pore surface leads to ail amazing potential in tuning functional properties, Clue to the combined properties of a thoroughly tailored pore system and the inherent features of thin films. These properties call be tailored to respond to changes in the environment, Such as relative humidity, making mesoporous hybrid thin films ail exciting prospect for several nanotechnology applications (e.g. sensors, actuators, separation devices). Here we present some basic concepts revolving around mesoporous films. We will first comment on the synthetic approach in the fabrication of these materials. Second, we will discuss the aspects regarding template organization and Surface functionalization. Third, we will review some applications illustrating the potentialities of theses self-assembled nanomaterials.
引用
收藏
页码:105 / +
页数:5
相关论文
共 66 条
[1]   Organically modified transition-metal oxide mesoporous thin films and xerogels [J].
Angelomé, PC ;
Soler-Illia, GJDAA .
CHEMISTRY OF MATERIALS, 2005, 17 (02) :322-331
[2]   Synthesis of phosphorus-free mesoporous titania via templating with amine surfactants [J].
Antonelli, DM .
MICROPOROUS AND MESOPOROUS MATERIALS, 1999, 30 (2-3) :315-319
[3]   Promises and problems of mesoscale materials chemistry or why meso? [J].
Antonietti, M ;
Ozin, GA .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (01) :28-41
[4]  
Barbe CJ, 1997, J AM CERAM SOC, V80, P3157, DOI 10.1111/j.1151-2916.1997.tb03245.x
[5]   Relative humidity and alcohol sensors based on mesoporous silica thin films synthesised from block copolymers [J].
Bearzotti, A ;
Bertolo, JM ;
Innocenzi, P ;
Falcaro, P ;
Traversa, E .
SENSORS AND ACTUATORS B-CHEMICAL, 2003, 95 (1-3) :107-110
[6]   A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].
BECK, JS ;
VARTULI, JC ;
ROTH, WJ ;
LEONOWICZ, ME ;
KRESGE, CT ;
SCHMITT, KD ;
CHU, CTW ;
OLSON, DH ;
SHEPPARD, EW ;
MCCULLEN, SB ;
HIGGINS, JB ;
SCHLENKER, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843
[7]  
Becker E. W., 1986, Microelectronic Engineering, V4, P35, DOI 10.1016/0167-9317(86)90004-3
[8]   3D quantum dot lattice inside mesoporous silica films [J].
Besson, S ;
Gacoin, T ;
Ricolleau, C ;
Jacquiod, C ;
Boilot, JP .
NANO LETTERS, 2002, 2 (04) :409-414
[9]   Self-assembly and crystallization Behavior of mesoporous, crystalline HfO2 thin films:: A model system for the generation of mesostructured transition-metal oxides [J].
Brezesinski, T ;
Smarsly, B ;
Iimura, K ;
Grosso, D ;
Boissiére, C ;
Amenitsch, H ;
Antonietti, M ;
Sanchez, C .
SMALL, 2005, 1 (8-9) :889-898
[10]   Morphological control of surfactant-templated metal oxide films [J].
Brinker, C. Jeffrey ;
Dunphy, Daffen R. .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2006, 11 (2-3) :126-132