Studies on synthesis and properties of poly(ferrocenyldimethylsilanes) and poly(ferrocenylmethylphenylsilanes)

被引:10
作者
Wang, L [1 ]
Ye, CY
Zhang, PY
Pan, J
Feng, LX
Wang, SF
Peng, TZ
机构
[1] Zhejiang Univ, Dept Polymer Sci & Engn, Hangzhou 310027, Peoples R China
[2] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
关键词
ring-opening polymerization; poly(ferrocenylmethylphenylsilanes); poly(ferrocenyldimethylsilanes);
D O I
10.1016/S0014-3057(01)00211-7
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Poly(ferrocenyldimethylsilane) and poly(ferrocenylmethylphenylsilane) have been prepared via the thermal ring-opening polymerization of the corresponding strained, silicon-bridged ferrocenophanes. It was found that the molecular weights of resultant polymers depend on the polymerization time, Their electrochemical behavior in aqueous electrolytes was investigated by cyclic voltammetry. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:531 / 535
页数:5
相关论文
共 6 条
[1]   RING-OPENING POLYMERIZATION OF STRAINED, RING-TILTED FERROCENOPHANES - A ROUTE TO HIGH-MOLECULAR-WEIGHT POLY(FERROCENYLSILANES) [J].
FOUCHER, DA ;
TANG, BZ ;
MANNERS, I .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (15) :6246-6248
[2]  
JI B, 2000, SPECIALITY PETROCHEM, V2, P44
[3]  
JI B, 2000, GONG NENG CAI LIAO, V31, P349
[4]   HIGH-MOLECULAR-WEIGHT POLY(FERROCENEDIYL SILANES) - SYNTHESIS AND ELECTROCHEMISTRY OF [-(C5H4)FE(C5H4)SIR2-]N, R = ME, ET, N-BU, N-HEX [J].
NGUYEN, MT ;
DIAZ, AF ;
DEMENTEV, VV ;
PANNELL, KH .
CHEMISTRY OF MATERIALS, 1993, 5 (10) :1389-1394
[5]   ELECTROCHEMICAL AND ELECTROCHROMIC PROPERTIES OF POLY(DIALKYLSILYLENEFERROCENYLENE) FILMS [J].
NGUYEN, MT ;
DIAZ, AF ;
DEMENTEV, VV ;
PANNELL, KH .
CHEMISTRY OF MATERIALS, 1994, 6 (07) :952-954
[6]   Synthesis, characterization, and properties of high molecular weight poly(methylated ferrocenylsilanes) and their charge transfer polymer salts with tetracyanoethylene [J].
Pudelski, JK ;
Foucher, DA ;
Honeyman, CH ;
Macdonald, PM ;
Manners, I ;
Barlow, S ;
OHare, D .
MACROMOLECULES, 1996, 29 (06) :1894-1903