Micellar, liquid crystalline and polymer systems based on surfactant and polyethylene imine as nanoreactors for the transfer of phosphoryl group

被引：13

作者：

Bakeeva, R ^{[1
]}

Kudryavtsev, D

Zakharova, L

Kudryavtseva, L

Raevska, A

Sopin, V

机构：

[1] Kazan State Technol Univ, Kazan 420015, Russia

[2] Russian Acad Sci, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia

[3] Joint Inst Nucl Res, Neutron Phys Lab, Dubna 141980, Moscow Region, Russia

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2001年 / 367卷

关键词：

kinetics; surfactant; polymer; liquid crystal;

D O I：

10.1080/10587250108028679

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the kinetic study of the hydrolysis of p-nitrophenyl alkyl chloromethylphosphonates and p-nitrophenyl diphenyl phosphate in the cationic surfactant-polyethylene imine-water system the dependence of the catalytic effect of the system on the nature of surfactants and substrates and the surfactant-polyethylene imine ratio was found. An appearance of liotropic mesophase in the surfactant -polymer solutions results in alteration in the reactivity of the substrates.

引用

页码：585 / 596

页数：12

共 17 条

[1] Kinetics and mechanism of aminolysis of phenyl acetates in aqueous solutions of poly(ethylenimine) [J].