Estimation of liquid-side mass transfer coefficient and liquid film thickness in a bubble column using single spherical bubble model

A macroscopic mass transfer model based on the unsteady-state liquid film mass transfer mechanism for a single spherical bubble was formulated. Analytical solution of the model equation was obtained in Laplace transform using surface renewal rates based on Danckwerts' surface age distribution function. The mass transfer coefficient, k(L), in a slurry bubble column under different operating conditions of temperature, pressure, gas flow rate, and solid concentration has been simulated using a program code BUBBLESIM in MATLAB (R), developed by the authors. The proposed model has been validated using secondary data for a slurry system under a wide range of operating conditions. The predicted values of k(L) show very good agreement with the experimental data within an average deviation of +/- 2%. The results show that the mass transfer coefficient, k(L), increased with increasing superficial gas velocity and temperature and decreased with increase in slurry concentration, while it changed slightly with pressure. Based on the present work, empirical correlations have been proposed for the prediction of in terms of dimensionless groups for H-2-, CO-, and CO2-paraffin-quartz sand systems under elevated temperatures (298-423K) and elevated pressures (1-3MPa) in a slurry bubble column.