Time-Resolved In Situ Liquid-Phase Atomic Force Microscopy and Infrared Nanospectroscopy during the Formation of Metal-Organic Framework Thin Films

被引：28

作者：

Mandemaker, Laurens D. B. ^{[1
]}

Filez, Matthias ^{[1
]}

Delen, Guusje ^{[1
]}

Tan, Huanshu ^{[3
]}

Zhang, Xuehua ^{[2
,3
]}

Lohse, Detlef ^{[3
,4
]}

Weckhuysen, Bert M. ^{[1
]}

机构：

[1] Univ Utrecht, Debye Inst Nanomat Sci, Univ Weg 99, NL-3584 CG Utrecht, Netherlands

[2] Univ Twente, JM Burgers Ctr Fluid Dynam, Max Planck Ctr Twente, Phys Fluids Grp, NL-7500 AE Enschede, Netherlands

[3] Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB T6G 1H9, Canada

[4] Max Planck Inst Dynam Self Org, D-37077 Gottingen, Germany

来源：

JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2018年 / 9卷 / 08期

基金：

欧洲研究理事会;

关键词：

COORDINATION POLYMERS; CRYSTAL-GROWTH; GENERATION; DEPOSITION; MONOLAYERS; EFFICIENCY; SURFACES; NANOFILM; STORAGE; DESIGN;

D O I：

10.1021/acs.jpclett.8b00203

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Metal organic framework (MOP) thin films show unmatched promise as smart membranes and photocatalytic coatings. However, their nucleation and growth resulting from intricate molecular assembly processes are not well understood yet are crucial to control the thin film properties. Here, we directly observe the nucleation and growth behavior of HKUST-1 thin films by real-time in situ AFM at different temperatures in a Cu-BTC solution. In combination with ex situ infrared (nano) spectroscopy, synthesis at 25 degrees C reveals initial nucleation of rapidly growing HKUST-1 islands surrounded by a continuously nucleating but slowly growing HKUST-1 carpet. Monitoring at 13 and 50 degrees C shows the strong impact of temperature on thin film formation, resulting in (partial) nucleation and growth inhibition. The nucleation and growth mechanisms as well as their kinetics provide insights to aid in future rational design of MOF thin films.

引用

页码：1838 / 1844

页数：13

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