Layer-by-layer deposition of tannic acid and Fe3+ cations is of electrostatic nature but almost ionic strength independent at pH 5

被引:48
作者
Ringwald, Christian [1 ]
Ball, Vincent [1 ,2 ]
机构
[1] Inst Natl Sante & Rech Med, Unite Mixte Rech 1121, Fac Med, F-67085 Strasbourg, France
[2] Fac Chirurg Dent, F-67000 Strasbourg, France
关键词
Tannic acid; Fe3+ cations; Coordination driven self-assembly; Influence of the ionic strength; POLYELECTROLYTE; MULTILAYER; POLYPHENOLS; BINDING; FILMS; COMPLEXES; KINETICS;
D O I
10.1016/j.jcis.2015.03.009
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The step-by-step assembly of tannic acid (TA) and of Fe3+ cations allows to produce films of controlled thickness using exclusively small multivalent ions. In the present investigation, it is shown that even if electrostatic interactions are dominant over ligand to metal charge transfer interactions in stabilizing such films, those electrostatic interactions display a small sensitivity to concentration in NaCl used as a supporting electrolyte as well as to the concentration in sodium acetate in the absence of NaCl. This finding highlights the strong stability of the films obtained through the step-by-step deposition of TA and Fe3+ cations. Complementarily, the films made from 6 deposition cycles of TA and Fe3+ cations do not form Prussian Blue when put in contact with hexacyanoferrate anions. This shows that Fe3+ is so tightly bound to the film that it is not able to form a coordination polymer with Fe(CN)(6)(4-) anions. (C) 2015 Elsevier Inc. All rights reserved.
引用
收藏
页码:119 / 126
页数:8
相关论文
共 25 条
  • [1] Amine oxidase-like activity of polyphenols - Mechanism and properties
    Akagawa, M
    Suyama, K
    [J]. EUROPEAN JOURNAL OF BIOCHEMISTRY, 2001, 268 (07): : 1953 - 1963
  • [2] Polyelectrolyte multilayer films made from polyallylamine and short polyphosphates: Influence of the surface treatment, ionic strength and nature of the electrolyte solution
    Apaydin, Kadir
    Laachachi, Abdelghani
    Bour, Jerome
    Toniazzo, Valerie
    Ruch, David
    Ball, Vincent
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2012, 415 : 274 - 280
  • [3] High loading capacity of Fe3+ cations in LBL films made from poly( ethyleneimine) and tannic acid: An alternative to coordination driven multistep assembly using polyphenols and Fe3+
    Ball, V.
    [J]. COLLOID AND INTERFACE SCIENCE COMMUNICATIONS, 2014, 3 : 1 - 4
  • [4] Phase Diagram of Sodium Hexametaphosphate and Poly(allylamine hydrochloride) Mixtures and In Situ Monitoring of Step-by-Step Deposition in This Polyelectrolyte System
    Ball, Vincent
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2015, 216 (01) : 85 - 94
  • [5] Cruz BH, 2000, ELECTROANAL, V12, P1130, DOI 10.1002/1521-4109(200010)12:14<1130::AID-ELAN1130>3.0.CO
  • [6] 2-7
  • [7] One-Step Assembly of Coordination Complexes for Versatile Film and Particle Engineering
    Ejima, Hirotaka
    Richardson, Joseph J.
    Liang, Kang
    Best, James P.
    van Koeverden, Martin P.
    Such, Georgina K.
    Cui, Jiwei
    Caruso, Frank
    [J]. SCIENCE, 2013, 341 (6142) : 154 - 157
  • [8] Hydrogen-bonded multilayers of a neutral polymer and a polyphenol
    Erel-Unal, Irem
    Sukhishvili, Svetlana A.
    [J]. MACROMOLECULES, 2008, 41 (11) : 3962 - 3970
  • [9] Natural polyphenols (vegetable tannins) as drugs: Possible modes of action
    Haslam, E
    [J]. JOURNAL OF NATURAL PRODUCTS, 1996, 59 (02): : 205 - 215
  • [10] Energy dissipation kinetics for protein and antibody-antigen adsorption under shear oscillation on a quartz crystal microbalance
    Hook, F
    Rodahl, M
    Brzezinski, P
    Kasemo, B
    [J]. LANGMUIR, 1998, 14 (04) : 729 - 734