Multi-site coordination ligands assembled on organostannoxane supports

被引：27

作者：

Chandrasekhar, V ^{[1
]}

Thilagar, P ^{[1
]}

Sasikumar, P ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2006年 / 691卷 / 08期

关键词：

organotin; stannoxane; coordination polymer; carboxylate ligand; multi-site coordination; weak hydrogen bonds; supramolecular formation;

D O I：

10.1016/j.jorganchem.2005.11.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of bis(pyrazol-1-yl) acetic acid LCOOH (1) (L = (PZ)(2)CH-) and bis(3,.5-dimethylpyrazol-1-yl)acetic acid L'COOH (2) (L = (3,5-Me(2)Pz)(2)CH-) with organotin oxide (hydroxide) precursors, n-BuSn(O)(OH), n-Bu2SnO, (n-Bu3Sn)(2)O and (Ph3Sn)(2)O has led to the isolation of several organotin compounds containing bispyrazolyl unit(s) on the periphery of the stannoxane structure [n-BuSn(O)O,CL]6 (3), [n-BuSn(O)O2CL'](6) (4), [n-Bu3SnO2CL](n) (5), [n-Bu3SnO2CL'](n) (6), [Ph3SnO2CL](n) (7). [Ph3SnO2CL'](n) (8), [{n-Bu2SnO2CL)(2) (9) and [{n-Bu2SnO2CL'}2O](2) (10). Compounds 5, 7, 9 and 10 have been structurally characterized by X-ray crystallography. In the solid state, these compounds possess interesting 3-D and 2-D supramolecular networks as a result of intermolecular C-H... 0, C-H (...) N, C-H (...) CI and C-H-... pi interactions. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：1681 / 1692

页数：12