Enhanced photovoltaic performance of dye sensitized solar cells using one dimensional ZnO nanorod decorated porous TiO2 film electrode

被引:30
作者
Yang, Long [1 ]
Ma, Qing-lan [1 ]
Cai, Yungao [2 ]
Huang, Yuan Ming [1 ]
机构
[1] Changzhou Univ, Sch Math & Phys, Changzhou 213164, Jiangsu, Peoples R China
[2] Baoshan Univ, Dept Sci & Technol, Baoshan 678000, Yunnan, Peoples R China
关键词
Dye sensitized solar cells; ZnO nanorod decorated porous TiO2 film; Dye adsorption amount; Energy barrier layer; Power conversion efficiency; HYDROTHERMAL METHOD; NANOTUBE ARRAYS; EFFICIENCY; NANOSTRUCTURES; GROWTH; LAYER;
D O I
10.1016/j.apsusc.2013.11.134
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Alow cost and effective working electrode with one dimensional ZnO nanorod grown on the porous TiO2 film is used to improve the power conversion efficiency of dye sensitized solar cells. The one dimensional ZnO nanorod is introduced into the porous TiO2 film by a simple and facile hydrothermal route, and the obtained composite film is characterized using the field-emission scan electron microscopy, X-ray diffractometer and photoluminescence spectroscopy. The photocurrent-voltage curves of fabricated dye sensitized solar cells are measured by a solar cell measurement system. Compared with the bare porous TiO2 film based dye sensitized solar cell, it is found that the power conversion efficiency of dye sensitized solar cell with ZnO nanorod decorated TiO2 porous film was improved by more than triple. It is mainly believed that the improved power conversion efficiency of dye sensitized solar cell is ascribed to the increased dye adsorption amount and formation of energy barrier between ZnO nanorod and porous TiO2 film. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:297 / 300
页数:4
相关论文
共 25 条
[1]   Solvothermal growth of high surface area mesoporous anatase TiO2 nanospheres and investigation of dye-sensitized solar cell properties [J].
Archana, J. ;
Navaneethan, M. ;
Hayakawa, Y. .
JOURNAL OF POWER SOURCES, 2013, 242 :803-810
[2]   Synthesis of graphene-ZnO nanorod nanocomposites with improved photoactivity and anti-photocorrosion [J].
Chen, Zhang ;
Zhang, Nan ;
Xu, Yi-Jun .
CRYSTENGCOMM, 2013, 15 (15) :3022-3030
[3]   Preparation of ZnO-coated TiO2 electrodes using dip coating and their applications in dye-sensitized solar cells [J].
Chou, Chuen-Shii ;
Chou, Feng-Cheng ;
Kang, Jhe-Yuan .
POWDER TECHNOLOGY, 2012, 215-16 :38-45
[4]   Annealing effects of ZnO nanorods on dye-sensitized solar cell efficiency [J].
Chung, Jooyoung ;
Lee, Juneyoung ;
Lim, Sangwoo .
PHYSICA B-CONDENSED MATTER, 2010, 405 (11) :2593-2598
[5]   Enhanced DSSC performance with high surface area thin anatase TiO2 nanoleaves [J].
Dhas, Vivek ;
Muduli, Subas ;
Agarkar, Shruti ;
Rana, Abhimanyu ;
Hannoyer, Beatrice ;
Banerjee, Rahul ;
Ogale, Satishchandra .
SOLAR ENERGY, 2011, 85 (06) :1213-1219
[6]   Dye-sensitized solar cells [J].
Grätzel, M .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2003, 4 (02) :145-153
[7]  
Hanna S., 2012, J PHYS CHEM C, V116, P2336
[8]   A simple method to grow one-dimensional ZnO nanostructures in air [J].
Huang, Yuan Ming ;
Ma, Qing-lan ;
Zhai, Bao-gai .
MATERIALS LETTERS, 2013, 93 :266-268
[9]   Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10% [J].
Ito, Seigo ;
Murakami, Takurou N. ;
Comte, Pascal ;
Liska, Paul ;
Graetzel, Carole ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
THIN SOLID FILMS, 2008, 516 (14) :4613-4619
[10]   Preparation of nanoporous MgO-Coated TiO2 nanoparticles and their application to the electrode of dye-sensitized solar cells [J].
Jung, HS ;
Lee, JK ;
Nastasi, M ;
Lee, SW ;
Kim, JY ;
Park, JS ;
Hong, KS ;
Shin, H .
LANGMUIR, 2005, 21 (23) :10332-10335