A Luminescent Material: La3Cl(CN2)O3 Doped with Eu3+ or Tb3+ Ions

被引：8

作者：

Kubus, Mariusz ^{[1
]}

Enseling, David ^{[2
]}

Juestel, Thomas ^{[2
]}

Meyer, H-Juergen ^{[1
]}

机构：

[1] Univ Tubingen, Inst Anorgan Chem, Abt Festkorperchem & Theoret Anorgan Chem, D-72076 Tubingen, Germany

[2] Fachhsch Munster, Lab Angew Mat Wissensch, D-48565 Steinfurt, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 18期

关键词：

Carbodiimide; Oxido ligands; Luminescence; Metathesis; STATE METATHESIS REACTIONS; RARE-EARTH DIOXYMONOCYANAMIDES; CRYSTAL-STRUCTURE; CARBODIIMIDES; CYANAMIDE; COMPOUND; LA2O2CN2; PR; LN;

D O I：

10.1002/ejic.201300224

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new carbodiimide compound La3Cl(CN2)O3 was obtained by a solid-state metathesis reaction from LaOCl and Li2(CN2) at 750 degrees C in a fused tube. Differential scanning calorimetry of the reaction mixture was performed. The crystal structure of La3Cl(CN2)O3 was determined by single-crystal X-ray diffraction studies (space group Cmcm, No. 63). The luminescent properties of the Eu3+- and Tb3+-doped compounds are reported.

引用

页码：3195 / 3199

页数：5

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